Portal de Periódicos da CAPES

Modification of the Surface Properties of Indium Tin Oxide with Benzylphosphonic Acids: A Joint Experimental and Theoretical Study

2009; Volume: 21; Issue: 44 Linguagem: Inglês

10.1002/adma.200900502

1521-4095

Peter J. Hotchkiss, Hong Li, Pavel Paramonov, Sergio A. Paniagua, Simon C. Jones, Neal R. Armstrong, Jean‐Luc Brédas, Seth R. Marder,

Organic Light-Emitting Diodes Research

Advanced MaterialsVolume 21, Issue 44 p. 4496-4501 Communication Modification of the Surface Properties of Indium Tin Oxide with Benzylphosphonic Acids: A Joint Experimental and Theoretical Study Peter J. Hotchkiss, Peter J. Hotchkiss School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA) Present address: Sandia National Laboratories, Albuquerque, NM 87185-1455, USASearch for more papers by this authorHong Li, Hong Li School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA)Search for more papers by this authorPavel B. Paramonov, Pavel B. Paramonov School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA) Present address: Department of Physics, University of Akron, Akron, OH 44325, USASearch for more papers by this authorSergio A. Paniagua, Sergio A. Paniagua Department of Chemistry University of Arizona Tucson, Arizona, 85721-0041, (USA)Search for more papers by this authorSimon C. Jones, Simon C. Jones School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA)Search for more papers by this authorNeal R. Armstrong, Corresponding Author Neal R. Armstrong [email protected] Department of Chemistry University of Arizona Tucson, Arizona, 85721-0041, (USA) Neal R. Armstrong, Department of Chemistry University of Arizona Tucson, Arizona, 85721-0041, (USA). Jean-Luc Brédas, School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA). Seth R. Marder, School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA).Search for more papers by this authorJean-Luc Brédas, Corresponding Author Jean-Luc Brédas [email protected] School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA) Neal R. Armstrong, Department of Chemistry University of Arizona Tucson, Arizona, 85721-0041, (USA). Jean-Luc Brédas, School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA). Seth R. Marder, School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA).Search for more papers by this authorSeth R. Marder, Corresponding Author Seth R. Marder [email protected] School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA) Neal R. Armstrong, Department of Chemistry University of Arizona Tucson, Arizona, 85721-0041, (USA). Jean-Luc Brédas, School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA). Seth R. Marder, School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA).Search for more papers by this author Peter J. Hotchkiss, Peter J. Hotchkiss School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA) Present address: Sandia National Laboratories, Albuquerque, NM 87185-1455, USASearch for more papers by this authorHong Li, Hong Li School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA)Search for more papers by this authorPavel B. Paramonov, Pavel B. Paramonov School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA) Present address: Department of Physics, University of Akron, Akron, OH 44325, USASearch for more papers by this authorSergio A. Paniagua, Sergio A. Paniagua Department of Chemistry University of Arizona Tucson, Arizona, 85721-0041, (USA)Search for more papers by this authorSimon C. Jones, Simon C. Jones School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA)Search for more papers by this authorNeal R. Armstrong, Corresponding Author Neal R. Armstrong [email protected] Department of Chemistry University of Arizona Tucson, Arizona, 85721-0041, (USA) Neal R. Armstrong, Department of Chemistry University of Arizona Tucson, Arizona, 85721-0041, (USA). Jean-Luc Brédas, School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA). Seth R. Marder, School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA).Search for more papers by this authorJean-Luc Brédas, Corresponding Author Jean-Luc Brédas [email protected] School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA) Neal R. Armstrong, Department of Chemistry University of Arizona Tucson, Arizona, 85721-0041, (USA). Jean-Luc Brédas, School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA). Seth R. Marder, School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA).Search for more papers by this authorSeth R. Marder, Corresponding Author Seth R. Marder [email protected] School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA) Neal R. Armstrong, Department of Chemistry University of Arizona Tucson, Arizona, 85721-0041, (USA). Jean-Luc Brédas, School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA). Seth R. Marder, School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta, Georgia 30332-0400, (USA).Search for more papers by this author First published: 24 November 2009 https://doi.org/10.1002/adma.200900502Citations: 142AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Benzylphosphonic acids with various fluorine substitutions are designed and synthesized. They are used to modify ITO such that the work function can be tuned over a range of 1.2 eV while keeping the surface energy relatively constant. The experimentally measured work function changes are also compared to and agree well with those estimated from DFT calculations. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description adma_200900502_sm_suppdata.pdf506.1 KB suppdata Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume21, Issue44November 26, 2009Pages 4496-4501 RelatedInformation