Modification of the Surface Properties of Indium Tin Oxide with Benzylphosphonic Acids: A Joint Experimental and Theoretical Study
2009; Volume: 21; Issue: 44 Linguagem: Inglês
10.1002/adma.200900502
ISSN1521-4095
AutoresPeter J. Hotchkiss, Hong Li, Pavel Paramonov, Sergio A. Paniagua, Simon C. Jones, Neal R. Armstrong, Jean‐Luc Brédas, Seth R. Marder,
Tópico(s)Organic Light-Emitting Diodes Research
ResumoBenzylphosphonic acids with various fluorine substitutions are designed and synthesized. They are used to modify ITO such that the work function can be tuned over a range of 1.2 eV while keeping the surface energy relatively constant. The experimentally measured work function changes are also compared to and agree well with those estimated from DFT calculations. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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