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Synthesis of Versatile Chiral N,P Ligands Derived from Pyridine and Quinoline

2003; Wiley; Volume: 43; Issue: 1 Linguagem: Inglês

10.1002/anie.200352755

1521-3773

William J. Drury, Nici Zimmermann, Martine Keenan, Masahiko Hayashi, Stefan Kaiser, Richard Goddard, Andreas Pfaltz,

Coordination Chemistry and Organometallics

Angewandte Chemie International EditionVolume 43, Issue 1 p. 70-74 Communication Synthesis of Versatile Chiral N,P Ligands Derived from Pyridine and Quinoline† William J. Drury III Dr., William J. Drury III Dr. Department of Chemistry, University of Basel, St. Johanns-Ring 19, 4056 Basel, Switzerland, Fax: (+41) 61-267-1103Search for more papers by this authorNicole Zimmermann Dr., Nicole Zimmermann Dr. Department of Chemistry, University of Basel, St. Johanns-Ring 19, 4056 Basel, Switzerland, Fax: (+41) 61-267-1103Search for more papers by this authorMartine Keenan Dr., Martine Keenan Dr. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, GermanySearch for more papers by this authorMasahiko Hayashi Dr., Masahiko Hayashi Dr. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, GermanySearch for more papers by this authorStefan Kaiser Dipl.-Chem., Stefan Kaiser Dipl.-Chem. Department of Chemistry, University of Basel, St. Johanns-Ring 19, 4056 Basel, Switzerland, Fax: (+41) 61-267-1103 X-Ray analyses.Search for more papers by this authorRichard Goddard Dr., Richard Goddard Dr. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany X-Ray analyses.Search for more papers by this authorAndreas Pfaltz Prof. Dr., Andreas Pfaltz Prof. Dr. andreas.pfaltz@unibas.ch Department of Chemistry, University of Basel, St. Johanns-Ring 19, 4056 Basel, Switzerland, Fax: (+41) 61-267-1103Search for more papers by this author William J. Drury III Dr., William J. Drury III Dr. Department of Chemistry, University of Basel, St. Johanns-Ring 19, 4056 Basel, Switzerland, Fax: (+41) 61-267-1103Search for more papers by this authorNicole Zimmermann Dr., Nicole Zimmermann Dr. Department of Chemistry, University of Basel, St. Johanns-Ring 19, 4056 Basel, Switzerland, Fax: (+41) 61-267-1103Search for more papers by this authorMartine Keenan Dr., Martine Keenan Dr. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, GermanySearch for more papers by this authorMasahiko Hayashi Dr., Masahiko Hayashi Dr. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, GermanySearch for more papers by this authorStefan Kaiser Dipl.-Chem., Stefan Kaiser Dipl.-Chem. Department of Chemistry, University of Basel, St. Johanns-Ring 19, 4056 Basel, Switzerland, Fax: (+41) 61-267-1103 X-Ray analyses.Search for more papers by this authorRichard Goddard Dr., Richard Goddard Dr. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany X-Ray analyses.Search for more papers by this authorAndreas Pfaltz Prof. Dr., Andreas Pfaltz Prof. Dr. andreas.pfaltz@unibas.ch Department of Chemistry, University of Basel, St. Johanns-Ring 19, 4056 Basel, Switzerland, Fax: (+41) 61-267-1103Search for more papers by this author First published: 17 December 2003 https://doi.org/10.1002/anie.200352755Citations: 138 † Financial support for this work from the American and Swiss National Science Foundations is gratefully acknowledged. N.Z. thanks the Fonds der Chemischen Industrie for a Kekulé fellowship. The authors kindly thank Dr. Thomas Lectka (The Johns Hopkins University) for helpful discussions. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Potent transition-metal complexes for asymmetric catalysis are formed from readily accessible N,P ligands constructed from basic N-heteroaryl building blocks (see structure). Their simple assembly should not be misconstrued: they posses several handles by which to tune both steric and electronic parameters. The potential of these ligands is demonstrated by the high levels of enantioselection they induce in such divergent processes as asymmetric hydrogenation and the Heck reaction. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2004/z52755_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume43, Issue1December 22, 2003Pages 70-74 RelatedInformation