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Synthesis and Structure Characterization of Copper Terephthalate Metal–Organic Frameworks

2009; Wiley; Volume: 2009; Issue: 16 Linguagem: Inglês

10.1002/ejic.200801224

1099-0682

Cantwell G. Carson, Kenneth I. Hardcastle, J. Schwartz, Xiaotao Liu, Christina Hoffmann, Rosario A. Gerhardt, Rina Tannenbaum,

Magnetism in coordination complexes

Abstract In this paper, we report on a high‐throughput (gram quantities) solvothermal method for the synthesis of copper terephthalate metal–organic frameworks in dmf. While the structure of MOF‐2 and some of the associated polymorphs are well known, we know of no equivalent structural studies for the isostructural copper terephthalate (Cu–tpa). The material we have made crystallizes in the C 2/ m space group. Cu–tpa also exhibits reversible solvent‐exchange properties. These properties make this material useful for potential applications in gas storage and catalysis applications. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)