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Combinatorial Catalysis with Bimetallic Complexes: Robust and Efficient Catalysts for Atom‐Transfer Radical Additions

2004; Wiley; Volume: 43; Issue: 12 Linguagem: Inglês

10.1002/anie.200353084

1521-3773

L. Quebatte, Rosario Scopelliti, Kay Severin,

Oxidative Organic Chemistry Reactions

A radical alternative? Two highly efficient catalysts for atom-transfer radical additions were discovered in a parallel screening of bimetallic complexes. Both catalysts contain a rhodium-centered fragment (blue), which is connected through three chloro bridges to a ruthenium-centered fragment (red).