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A Highly Symmetric Sixfold Cycloaddition Product of Fullerene C 60

1995; Wiley; Volume: 34; Issue: 1 Linguagem: Inglês

10.1002/anie.199500871

1521-3773

Bernhard Kräutler, Josef Maynollo,

Advanced Physical and Chemical Molecular Interactions

Angewandte Chemie International Edition in EnglishVolume 34, Issue 1 p. 87-88 Communication A Highly Symmetric Sixfold Cycloaddition Product of Fullerene C60† Prof. Dr. Bernhard Kräutler, Corresponding Author Prof. Dr. Bernhard Kräutler Institut für Organische Chemie der Universität, Innrain 52a, A-6020 Innsbruck (Austria), Telefax: Int. code + (512)507-2892Institut für Organische Chemie der Universität, Innrain 52a, A-6020 Innsbruck (Austria), Telefax: Int. code + (512)507-2892Search for more papers by this authorMag. Josef Maynollo, Mag. Josef Maynollo Institut für Organische Chemie der Universität, Innrain 52a, A-6020 Innsbruck (Austria), Telefax: Int. code + (512)507-2892Search for more papers by this author Prof. Dr. Bernhard Kräutler, Corresponding Author Prof. Dr. Bernhard Kräutler Institut für Organische Chemie der Universität, Innrain 52a, A-6020 Innsbruck (Austria), Telefax: Int. code + (512)507-2892Institut für Organische Chemie der Universität, Innrain 52a, A-6020 Innsbruck (Austria), Telefax: Int. code + (512)507-2892Search for more papers by this authorMag. Josef Maynollo, Mag. Josef Maynollo Institut für Organische Chemie der Universität, Innrain 52a, A-6020 Innsbruck (Austria), Telefax: Int. code + (512)507-2892Search for more papers by this author First published: January 16, 1995 https://doi.org/10.1002/anie.199500871Citations: 73 † We would like to thank Dr. Robert Konrat and Mag. Walter Mühlecker for measuring NMR spectra, Rolf Häfliger and Dr. Walter Amrein (ETH, Zürich) for FAB mass spectra, Dr. Ludwig Call for his pertinent comments, Mag. Michael Schranz and Dr. Michael Puchberger for researching bibliographical data, and Fluka AG (Buchs, Switzerland) for providing a sample of C60.– FAB = fast atom bombardment, NOBA = ortho-nitrobenzyl alcohol. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract In one step and with 26% yield, a sixfold Diels-Alder product is formed from buckminsterfullerene C60 and 2,3-dimethyl-1,3-butadiene. This first direct synthesis of a highly symmetric, exohedrally sixfold substituted fullerene addition product is remarkably simple. The components were heated in ortho-dichlorobenzene at roughly 110°C for ten days, and the product was purified by column chromatography. Citing Literature Volume34, Issue1January 16, 1995Pages 87-88 This article also appears in:Fullerenes RelatedInformation