Synthesis of perfluoroalkyl-containing multifunctional groups compounds for textile finishing
2002; Elsevier BV; Volume: 113; Issue: 1 Linguagem: Inglês
10.1016/s0022-1139(01)00495-x
ISSN1873-3328
AutoresFeng‐Ling Qing, Min Ji, Ronghua Lu, Kelu Yan, Zhiping Mao,
Tópico(s)Synthesis and properties of polymers
ResumoA new kind of perfluoroalkyl-containing multifunctional groups compound was designed. Treatment of 1H,1H,2H,2H-perfluorooctyltrichlorosilane (4) with allylmagnesium bromide provided key intermediate 1H,1H,2H,2H-perfluorooctyltriallylsilane (2). Hydroboration followed by oxidation, epoxidation and dihydroxylation of 2 gave perfluoroalkyl-containing multifunctional groups compound 1a, 1b and 1c, respectively.
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