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Artigo Revisado por pares
BIBTEX RIS

Palladium‐Catalyzed Reductive Carbonylation of Aryl Halides with N ‐Formylsaccharin as a CO Source

2013; Wiley; Volume: 52; Issue: 33 Linguagem: Inglês

10.1002/anie.201303926

ISSN

1521-3773

Autores

Tsuyoshi Ueda, Hideyuki Konishi, Kei Manabe,

Tópico(s)

Asymmetric Hydrogenation and Catalysis

Resumo

Easy peasy: The title reaction employs N-formylsaccharin, which is an easily accessible crystalline compound, as an effective CO source. The reactions proceed with a small excess of the CO source at moderate temperatures and were successfully applied to a wide range of aryl bromides. DMF=N,N-dimethylformamide, dppb=1,4-bis-(diphenylphosphino)butane.

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