Solid‐State Conversion of the Solvated Dimer [{ t BuZn(μ‐O t Bu)(thf)} 2 ] into a Long Overlooked Trimeric [{ t BuZnO t Bu} 3 ] Species
2010; Wiley; Volume: 49; Issue: 44 Linguagem: Inglês
10.1002/anie.201004504
ISSN1521-3773
AutoresJanusz Lewiński, Michał Dutkiewicz, Michał Lesiuk, W. Sliwinski, Karolina Zelga, Iwona Justyniak, Janusz Lipkowski,
Tópico(s)Coordination Chemistry and Organometallics
ResumoAngewandte Chemie International EditionVolume 49, Issue 44 p. 8266-8269 Communication Solid-State Conversion of the Solvated Dimer [{tBuZn(μ-OtBu)(thf)}2] into a Long Overlooked Trimeric [{tBuZnOtBu}3] Species† Prof. Dr. Janusz Lewiński, Prof. Dr. Janusz Lewiński [email protected] Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland), Fax: (+48) 22-234-7279 http://lewin.ch.pw.edu.pl Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw (Poland)Search for more papers by this authorMichał Dutkiewicz, Michał Dutkiewicz Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland), Fax: (+48) 22-234-7279 http://lewin.ch.pw.edu.plSearch for more papers by this authorMichał Lesiuk, Michał Lesiuk Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland), Fax: (+48) 22-234-7279 http://lewin.ch.pw.edu.plSearch for more papers by this authorDr. Witold Śliwiński, Dr. Witold Śliwiński Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland), Fax: (+48) 22-234-7279 http://lewin.ch.pw.edu.plSearch for more papers by this authorDr. Karolina Zelga, Dr. Karolina Zelga Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland), Fax: (+48) 22-234-7279 http://lewin.ch.pw.edu.plSearch for more papers by this authorDr. Iwona Justyniak, Dr. Iwona Justyniak Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw (Poland)Search for more papers by this authorProf. Dr. Janusz Lipkowski, Prof. Dr. Janusz Lipkowski Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw (Poland)Search for more papers by this author Prof. Dr. Janusz Lewiński, Prof. Dr. Janusz Lewiński [email protected] Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland), Fax: (+48) 22-234-7279 http://lewin.ch.pw.edu.pl Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw (Poland)Search for more papers by this authorMichał Dutkiewicz, Michał Dutkiewicz Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland), Fax: (+48) 22-234-7279 http://lewin.ch.pw.edu.plSearch for more papers by this authorMichał Lesiuk, Michał Lesiuk Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland), Fax: (+48) 22-234-7279 http://lewin.ch.pw.edu.plSearch for more papers by this authorDr. Witold Śliwiński, Dr. Witold Śliwiński Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland), Fax: (+48) 22-234-7279 http://lewin.ch.pw.edu.plSearch for more papers by this authorDr. Karolina Zelga, Dr. Karolina Zelga Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland), Fax: (+48) 22-234-7279 http://lewin.ch.pw.edu.plSearch for more papers by this authorDr. Iwona Justyniak, Dr. Iwona Justyniak Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw (Poland)Search for more papers by this authorProf. Dr. Janusz Lipkowski, Prof. Dr. Janusz Lipkowski Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw (Poland)Search for more papers by this author First published: 20 September 2010 https://doi.org/10.1002/anie.201004504Citations: 34 † We gratefully acknowledge funding from the Ministry of Science and Higher Education (Grant No. N204 164336), the European Union (within the European Regional Development Fund through the grant Innovative Economy POIG.01.01.02-00-008/08) (I.J.,M.D., and M.L.), and the Foundation for Polish Science (K.Z.). We are grateful to Prof. Z. Kaszkur for PXRD measurements. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Zinc links: Solid-state desolvation of the dimeric alkoxide [{tBuZn(μ-OtBu)(thf)}2] leads to a trimer [{tBuZnOtBu}3] with a unique core structure; subsequent grinding affords the tetrameric cubane [{tBuZnOtBu}4]. This approach demonstrates a new direction in the generation of metal alkoxide clusters. Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201004504_sm_miscellaneous_information.pdf741.3 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 1aE. Frankland, Justus Liebigs Ann. 1849, 71, 171–213; 1bE. Frankland, J. Chem. Soc. 1850, 2, 263–296. 2 2aM. M. Olmstead, P. P. Power, S. C. Shoner, J. Am. Chem. Soc. 1991, 113, 3379–3385; 2bJ. Boersma, Comprehensive Organometallic Chemistry, Vol. 2 (Eds.: ), Pergamon, Oxford, 1984, chap. 16. 3 3aK. Su, T. D. Tilley, M. J. Sailor, J. Am. Chem. Soc. 1996, 118, 3459–3468; 3bC. G. Kim, K. Sung, T. M. 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