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Asymmetric, Protecting‐Group‐Free Total Synthesis of (−)‐Englerin A

2010; Wiley; Volume: 49; Issue: 20 Linguagem: Inglês

10.1002/anie.201000888

1521-3773

Qianghui Zhou, Xiaofei Chen, Dawei Ma,

Phytochemistry and Bioactivity Studies

Angewandte Chemie International EditionVolume 49, Issue 20 p. 3513-3516 Communication Asymmetric, Protecting-Group-Free Total Synthesis of (−)-Englerin A† Qianghui Zhou, Qianghui Zhou State Key Laboratory of Bioorganic & Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032 (China), Fax: (+86) 21-6416-6128Search for more papers by this authorXiaofei Chen, Xiaofei Chen State Key Laboratory of Bioorganic & Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032 (China), Fax: (+86) 21-6416-6128Search for more papers by this authorDawei Ma Prof. Dr., Dawei Ma Prof. Dr. [email protected] State Key Laboratory of Bioorganic & Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032 (China), Fax: (+86) 21-6416-6128Search for more papers by this author Qianghui Zhou, Qianghui Zhou State Key Laboratory of Bioorganic & Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032 (China), Fax: (+86) 21-6416-6128Search for more papers by this authorXiaofei Chen, Xiaofei Chen State Key Laboratory of Bioorganic & Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032 (China), Fax: (+86) 21-6416-6128Search for more papers by this authorDawei Ma Prof. Dr., Dawei Ma Prof. Dr. [email protected] State Key Laboratory of Bioorganic & Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032 (China), Fax: (+86) 21-6416-6128Search for more papers by this author First published: 28 April 2010 https://doi.org/10.1002/anie.201000888Citations: 180 † We are grateful to National Basic Research Program of China (973 Program, grant 2010CB833200), Chinese Academy of Sciences and the National Natural Science Foundation of China (grant 20632050 & 20921091) for their financial support. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract The golden touch: Total synthesis of natural (−)-englerin A from (R)-citronellal has been achieved using a gold-catalyzed cyclization as the key step (see scheme). No protecting-group manipulations were required in the synthetic sequence. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201000888_sm_miscellaneous_information.pdf778.3 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume49, Issue20May 3, 2010Pages 3513-3516 RelatedInformation