Derivatives of 2-iodoxybenzenesulfonic acid: new pseudocyclic hypervalent iodine reagents
2004; ARKAT USA, Inc.; Volume: 2005; Issue: 4 Linguagem: Inglês
10.3998/ark.5550190.0006.402
ISSN1551-7012
AutoresViktor V. Zhdankin, Rostyslav N. Goncharenko, Dmitry N. Litvinov, Alexey Y. Koposov,
Tópico(s)Synthesis and Biological Evaluation
ResumoAmides and esters of 2-iodoxybenzenesulfonic acid were prepared by dimethyldioxirane oxidation of the respective monovalent iodine derivatives and isolated as stable, microcrystalline compounds.These new hypervalent iodine reagents with a pseudobenziodoxole structure are efficient oxidizers of alcohols, secondary amines and sulfides.
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