A Helical π‐Radical‐Cation Column in the Double Helix of Mellitate Anions
2004; Volume: 16; Issue: 20 Linguagem: Inglês
10.1002/adma.200400495
ISSN1521-4095
AutoresNobuhiko P. Kobayashi, T. Naito, Tamotsu Inabe,
Tópico(s)Solid-state spectroscopy and crystallography
ResumoAdvanced MaterialsVolume 16, Issue 20 p. 1803-1806 Communication A Helical π-Radical-Cation Column in the Double Helix of Mellitate Anions† N. Kobayashi, N. Kobayashi Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo 060-0810, JapanSearch for more papers by this authorT. Naito, T. Naito Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo 060-0810, JapanSearch for more papers by this authorT. Inabe, T. Inabe [email protected] Search for more papers by this author N. Kobayashi, N. Kobayashi Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo 060-0810, JapanSearch for more papers by this authorT. Naito, T. Naito Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo 060-0810, JapanSearch for more papers by this authorT. Inabe, T. Inabe [email protected] Search for more papers by this author First published: 08 November 2004 https://doi.org/10.1002/adma.200400495Citations: 27 † This work was supported in part by a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science, and Technology. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract A tetrathiafulvalene (TTF) π-radical-cation salt with a unique helical-column structure (see Figure) was constructed using a supramolecular double-helix network of mellitate anions. The TTF radical tends to dimerize in a one- dimensional column, but a twisting distortion induces a kink defect. Utilizing the supramolecular network of a counterion is a promising method for the design of novel functional molecular materials. Citing Literature Volume16, Issue20October, 2004Pages 1803-1806 RelatedInformation
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