Artigo Acesso aberto Revisado por pares

Electrochemical performance of SnO 2 :Sb-MWCNT nanocomposites for Li-ion batteries

2014; Wiley; Volume: 38; Issue: 4 Linguagem: Inglês

10.1002/er.3132

ISSN

1099-114X

Autores

O. Cevher, Mehmet Oğuz Güler, U. Tocoglu, Hatem Akbulut,

Tópico(s)

Gas Sensing Nanomaterials and Sensors

Resumo

International Journal of Energy ResearchVolume 38, Issue 4 p. 499-508 Special Issue on Nano Energy Technologies Electrochemical performance of SnO2:Sb–MWCNT nanocomposites for Li-ion batteries Ozgur Cevher, Corresponding Author Ozgur Cevher Sakarya University, Engineering Faculty, Department of Metallurgical and Material Engineering, Esentepe Campus, Sakarya, Turkey Correspondence: Ozgur Cevher, Sakarya University, Engineering Faculty, Department of Metallurgical and Material Engineering, Esentepe Campus, Sakarya, Turkey E-mail: [email protected]Search for more papers by this authorMehmet Oguz Guler, Mehmet Oguz Guler Sakarya University, Engineering Faculty, Department of Metallurgical and Material Engineering, Esentepe Campus, Sakarya, TurkeySearch for more papers by this authorUbeyd Tocoglu, Ubeyd Tocoglu Sakarya University, Engineering Faculty, Department of Metallurgical and Material Engineering, Esentepe Campus, Sakarya, TurkeySearch for more papers by this authorHatem Akbulut, Hatem Akbulut Sakarya University, Engineering Faculty, Department of Metallurgical and Material Engineering, Esentepe Campus, Sakarya, TurkeySearch for more papers by this author Ozgur Cevher, Corresponding Author Ozgur Cevher Sakarya University, Engineering Faculty, Department of Metallurgical and Material Engineering, Esentepe Campus, Sakarya, Turkey Correspondence: Ozgur Cevher, Sakarya University, Engineering Faculty, Department of Metallurgical and Material Engineering, Esentepe Campus, Sakarya, Turkey E-mail: [email protected]Search for more papers by this authorMehmet Oguz Guler, Mehmet Oguz Guler Sakarya University, Engineering Faculty, Department of Metallurgical and Material Engineering, Esentepe Campus, Sakarya, TurkeySearch for more papers by this authorUbeyd Tocoglu, Ubeyd Tocoglu Sakarya University, Engineering Faculty, Department of Metallurgical and Material Engineering, Esentepe Campus, Sakarya, TurkeySearch for more papers by this authorHatem Akbulut, Hatem Akbulut Sakarya University, Engineering Faculty, Department of Metallurgical and Material Engineering, Esentepe Campus, Sakarya, TurkeySearch for more papers by this author First published: 03 January 2014 https://doi.org/10.1002/er.3132Citations: 15Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL SUMMARY In this study, SnO2:Sb coating on Cr-coated stainless steel and multiwall carbon nanotube (MWCNT) buckypaper substrates were prepared as anode materials using a radio frequency (RF) magnetron sputtering process for lithium-ion batteries. The nanocomposites were characterized with field-emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction and electrochemical test facilities. The evaluation of the electrochemical performance in lithium-ion batteries showed that the SnO2:Sb–MWCNT nanocomposites have shown reversible discharge capacities of 701 mAh g−1, 732 mAh g−1 and 753 mAh g−1 for different RF powers (75 W, 100 W and 125 W), respectively, after 100 cycles. The high-capacity retention and cyclability ascribed to the good dispersion, high conductivity and fine particle size of SnO2:Sb on MWCNTs. Besides, the MWCNTs in SnO2:Sb act as a load carrying buffer component and behave like a flexible reinforcement, alleviating the electrode dilapidation resulted from volume change during the lithium insertion and de-insertion. Copyright © 2014 John Wiley & Sons, Ltd. REFERENCES 1 Arlinghaus FJ. Energy bands in stannic oxide (SnO2). Journal of Physics and Chemistry of Solids 1974; 35: 931– 935. 2 Batzill M, Diebold U. The surface and materials science of tin oxide. Progress in Surface Science 2005; 79: 47– 154. 3 Haridas D, Sreenivas K, Gupta V. Improved response characteristics of SnO2 thin film loaded with nanoscale catalysts for LPG detection. Sensors and Actuators B 2008; 133: 270– 275. 4 Ayllon JA, Lira-Cantu M. Application of MEH/SnO2 bilayers as hybrid solar cell. Applied Physics A 2009; 95: 249– 255. 5 Presley RE, Munsee CL, Park CH, Hong D, Wager JF, Keszler DA. Tin oxide transparent thin-film transistors. Journal of Physics D: Applied Physics 2004; 37: 2810– 2813. 6 Cássia-Santos MR, Sousa VC, Oliveira MM, Sensato FR, Bacelar WK, Gomes JW, Longo E, Leite ER, Varela JA. Recent research developments in SnO2-based varistors. Materials Chemistry and Physics 2005; 90: 1– 9. 7 Chopra KL, Major S, Pandya DK. Transparent conductors-A status review. Thin Solid Films 1983; 102: 1– 46. 8 Aguilar-Leyva J, Maldonado A, Olvera ML. Gas-sensing characteristics of undoped-SnO2 thin films and Ag/SnO2 and SnO2/Ag structures in a propane atmosphere. Materials Characterization 2007; 58: 740– 744. 9 Rajpure KY, Kusumade MN, Neumann-Spallart MN, Bhosale CH. Effect of Sb doping on properties of conductive spray deposited SnO2 thin films. Materials Chemistry and Physics 2000; 64: 184– 188. 10 Kawabe T, Shimomura S, Karasuda T, Tabata K, Suzuki E, Yamaguchi Y. Photoemission study of dissociatively adsorbed methane on a pre-oxidized SnO2 thin film. Surface Science 2000; 448: 101– 107. 11 Stjerna B, Olsson E, Granqvist CG. Optical and electrical properties of radio frequency sputtered tin oxide films doped with oxygen vacancies, F, Sb, or Mo. Journal of Applied Physics 1994; 76: 3797– 3818. 12 Jain G, Kumae R. Electrical and optical properties of tin oxide and antimony doped tin oxide films. Optical Materials 2004; 26: 27– 41. 13 Zhang D, Tao L, Deng Z, Zhang J, Chen L. Surface morphologies and properties of pure and antimony-doped tin oxide films derived by sol–gel dip-coating processing. Materials Chemistry & Physics 2006; 100: 275– 280. 14 Zhang D, Deng Z, Zhang J, Chen L. Microstructure and electrical properties of antimony-doped tin oxide thin film deposited by sol–gel process. Materials Chemistry & Physics 2006; 98: 353– 357. 15 Todd ADW, Ferguson PP, Fleischauer MD, Dahn JR. Tin-based materials as negative electrodes for Li-ion batteries: Combinatorial approaches and mechanical methods. International Journal of Energy Research 2010; 34: 535– 555. 16 Karimi G, Li X. Thermal management of lithium-ion batteries for electric vehicles. International Journal of Energy Research 2013; 37: 13– 24. 17 Lux SF, Schmuck M, Jeong S, Passerini S, Winter M, Balducci A. Li-ion anodes in air-stable and hydrophobic ionic liquid-based electrolyte for safer and greener batteries. International Journal of Energy Research 2010; 34: 97– 106. 18 Abraham DP, Dees DW, Christophersen J, Ho C, Jansen AN. Performance of high-power lithium-ion cells under pulse discharge and charge conditions. International Journal of Energy Research 2010; 34: 190– 203. 19 Ying Z, Wan Q, Cao H, Song ZT, Feng SL. Characterization of SnO2 nanowires as an anode material for Li-ion batteries. Applied Physics Letters 2005; 87:113108. 20 Idota Y, Kubota T, Matsufuji A, Maekawa Y, Miyasaki T. Tin-Based Amorphous Oxide: A High-Capacity Lithium-Ion-Storage Material. Science 1997; 276: 1395– 1397. 21 Moon T, Kim C, Hwang ST, Park B. Electrochemical Properties of Disordered-Carbon-Coated SnO2 Nanoparticles for Li Rechargeable Batteries. Electrochemical and Solid-State Letters 2006; 9: A408– A411. 22 Idota Y, Kubota T, Matsufuji A, Maekawa Y, Miyasaka T. Tin-Based Amorphous Oxide: A High-Capacity Lithium-Ion-Storage Material. Science 1997; 276: 1395– 1397. 23 Li H, Huang XJ, Chen LQ, Wu ZG, Liang Y. A High Capacity Nano-Si Composite Anode Material for Lithium Rechargeable Batteries. Electrochemical and Solid-State Letters 1999; 2: 547– 549. 24 Lee JY, Zhang RF, Liu ZL. Lithium intercalation and deintercalation reactions in synthetic graphite containing a high dispersion of SnO. Electrochemical and Solid-State Letters 2000; 3: 167– 170. 25 Lee WH, Son HC, Reucroft PJ, Lee JG, Park JW. Effect of working pressure on the electrochemical performance of thin filmSnO2 microbattery anodes deposited by radio frequency magnetron sputtering. Journal of Materials Science Letters 2001; 20: 39– 41. 26 An G, Na N, Zhang X, Miao Z, Miao S, Ding K. SnO2/carbon nanotube nanocomposites synthesized in supercritical fluids: highly efficient materials for use as a chemical sensor and as the anode of a lithium-ion battery. Nanotechnology 2007; 18: 435707-1– 435707-12. 27 Fu Y, Ma R, Shu Y, Cao Z, Ma X. Preparation and characterization of SnO2/carbon nanotube composite for lithium ion battery applications. Materials Letters 2009; 63: 1946– 1948. 28 Han L, Wu W, Kirk FL, Luo J, Maye MM, Kariuki NN. A direct route toward assembly of nanoparticles-carbon nanotubes composite materials. Langmuir 2004; 20: 6019– 6025. 29 Chen WX, Lee JY, Liu ZL. Preparation of Pt and PtRu nanoparticles supported on carbon nanotubes by microwave-assisted heating polyolprocess. Materials Letters 2004; 58: 3166– 3169. 30 Chen WX, Lee JY, Liu ZL. The nanocomposites of carbon nanotubes with Sb and SnSb0.5 as Li-ion battery anodes. Carbon 2003; 41: 959– 966. 31 Chen ML, Bae JS, Yoon HS, Lim CS, Oh WC. The Photodegradation Effect of Organic Dye for Metal Oxide (Cr2O3, MgO and V2O3) Treated CNT/TiO2 Composites. Bulletin of the Korean Chemical Society 2011; 32: 815– 820. 32 Hafner J, Cheung CL, Oosterkamp TH, Lieber CM. High-Yield Assembly of Individual Single-Walled Carbon Nanotube Tips for Scanning Probe Microscopies. The Journal of Physical Chemistry. B 2001; 105: 743– 746. 33 Do QH, Zeng C, Zhang C, Wang B, Zheng J. Supercritical fluid deposition of vanadium oxide on multi-walled carbon nanotube buckypaper for supercapacitor electrode application. Nanotechnology 2011; 22: 365– 402. 34 Yu J, Chua D. Effective electron emitters by molybdenum oxide-coated carbon nanotubes core-shell nanostructures. Journal of Materials Science 2011; 46: 4858– 4863. 35 Liang YX. Low-resistance gas sensors fabricated from multiwalled carbon nanotubes coated with a thin tin oxide layer. Applied Physics Letters 2004; 85: 666– 668. 36 Chen Y. The enhanced ethanol sensing properties of multi-walled carbon nanotubes/SnO2 core/shell nanostructures. Nanotechnology 2006; 17: 3012– 3017. 37 Liu YL. Gas sensing properties of SnO2 coated multi-walled carbon nanotubes. Thin Solid Films 2006; 497: 355– 360. 38 Zhang FF. Assay for uric acid level in rat striatum by a reagentless biosensor based on functionalized multi-wall carbon nanotubes with tin oxide. Analytical and Bioanalytical Chemistry 2005; 382: 1368– 1373. 39 Waki K. Self-organized Pt/SnO2 electrocatalysts on multiwalled carbon nanotubes. Electrochemical and Solid-State Letters 2005; 8: A489– A491. 40 Xie J. Synthesis and characterization of high surface area tin oxide/functionalized carbon nanotubes composite as anode materials. Materials Chemistry and Physics 2005; 91: 274– 280. 41 Saipriya S, Sultan M, Singh R. Effect of environment and heat treatment on the optical properties of RF-sputtered SnO2 thin films. Physica B 2011; 406: 812– 817. 42 Lee SU, Boo JH, Hong B. Structural, Electrical, and Optical Properties of SnO2:Sb Films Prepared on Flexible Substrate at Room Temperature. Japanese Journal of Applied Physics 2011; 50: 01AB10-1– 01AB10-5. 43 Peng LP, Fang L, Yang XF, Ruan HB, Li YJ, Huang QL, Kong CY. Characteristics of ZnO:In thin films prepared by RF magnetron sputtering. Physica E: Low-dimensional Systems and Nanostructures 2009; 41: 1819– 1823. 44 Cullity BD. Elements of X-Ray Diffraction. Addison-Wesley Publishing Company: Massachusetts, 1956. 45 Zhang Y, Franklin NW, Chen RJ, Dai H. Metal coating on suspended carbon nanotubes and its implication to metal-tube interaction. Chemical Physics Letters 2000; 331: 35– 41. 46 Satishkumar BC, Vogl EM, Govindaraj A, Rao CNR. The decoration of carbon nanotubes by metal nanoparticles. Journal of Physics D: Applied physics 1996; 29: 3173– 3176. 47 Mao-Shui L, Zhi-Yong P, Xian-Wu X, Ying D, Sheng-Hao H. Effect of RF power on the properties of transparent conducting zirconium-doped zinc oxide. Chinese Physics 2007; 16: 548– 552. 48 Li C, Zhang R, Li W, Zhao L, Hu S, Rao M, Xu J. Ultrasonic-electrodeposited Sn-CNTs composite used as anode material for lithium ion battery. The Transactions of Nonferrous Metals Society of China 2007; 17: 934– 936. 49 Chen MH, Huang ZC, Wu GT, Zhu GM, You JK, Lin ZG. Synthesis and characterization of SnO-carbon nanotube composite as anode material for lithium-ion batteries. Materials Research Bulletin 2003; 38: 831– 836. 50 Santos-Pena J, Brousse T, Sanchez L, Morales J, Schleic DM. Antimony Doping Effect on the Electrochemical Behavior of SnO2 Thin Film Electrode. Journal of Power Sources 2001; 97-98: 232– 234. 51 Wang Y, Chen T. Nonaqueous and template-free synthesis of Sb doped SnO2 microspheres and their application to lithium-ion battery anode. Electrochimica Acta 2009; 54: 3510– 3515. 52 Liu P, Lee S-H, Tracy CE, Yan Y, Turner JA. Preparation and lithium insertion properties of mesoporous vanadium oxides. Advanced Materials 2002; 14: 27– 30. 53 Exnar I, Kavan L, Huang SY, Grätzel M. Novel 2 V rocking-chair lithium battery based on nano-crystalline titanium dioxide. Journal of Power Sources 1997; 68: 720– 722. 54 Yang S, Song H, Chen X. Nanosized tin and tin oxides loaded expanded mesocarbon microbeads as negative electrode material for lithium-ion batteries. Journal of Power Sources 2007; 173: 487– 494. 55 Yang S, Huo J, Song H, Chen X. A comparative study of electrochemical properties of two kinds of carbon nanotubes as anode materials for lithium ion batteries. Electrochimica Acta 2008; 53: 2238– 2244. Citing Literature Volume38, Issue4Special Issue: Nano energy technologies25 March 2014Pages 499-508 ReferencesRelatedInformation

Referência(s)