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Absolute intensities of CO_2 lines in the 3140–3410-cm^−1 spectral region

1988; Optica Publishing Group; Volume: 27; Issue: 8 Linguagem: Inglês

10.1364/ao.27.001588

0003-6935

D. Chris Benner, V. Malathy Devi, C. P. Rinsland, Penelope S. Ferry-Leeper,

Scientific Measurement and Uncertainty Evaluation

Absolute intensities for 430 transitions belonging to eleven rotation-vibration bands of (12)C(16)O(2),(13)C(16)O(2) and(16)O(12)C(18)O in the 3140-3410-cm(-1) spectral region have been determined by analyzing spectra recorded at 0.01-cm(-1) resolution with the Fourier transform spectrometer in the McMath solar telescope complex at the National Solar Observatory on Kitt Peak. The data were recorded at room temperature and low pressures (<10 Torr) using a natural sample of carbon dioxide. Intensities were derived using a nonlinear least-squares spectral fitting procedure, and the values obtained for each band have been analyzed to determine the vibrational band intensity and nonrigid rotor coefficients. An alternative mathematical formulation is shown in the case of bands for which the Coriolis effect is large and the Q-branch line intensities were not determinate either because they were severely blended or absent from the spectra. Comparisons are made between the results obtained in this study and other published values.