Gold‐Catalyzed Halogenation of Aromatics by N ‐Halosuccinimides
2010; Wiley; Volume: 49; Issue: 11 Linguagem: Inglês
10.1002/anie.200906699
ISSN1521-3773
AutoresFanyang Mo, Jerry Mingtao Yan, Di Qiu, Fei Li, Yan Zhang, Jianbo Wang,
Tópico(s)Vanadium and Halogenation Chemistry
ResumoGolden bromination: A highly efficient and mild AuCl3-catalyzed bromination of aromatic rings with N-bromosuccinimide (NBS) has been developed. This method works with a low catalyst loading (down to 0.01 mol %) and can be combined with transition metal catalyzed transformations to deliver various aryl products.
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