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System with Potential Dual Modes of Metal–Ligand Cooperation: Highly Catalytically Active Pyridine‐Based PNNH–Ru Pincer Complexes

2014; Wiley; Volume: 20; Issue: 48 Linguagem: Inglês

10.1002/chem.201405295

1521-3765

Eran Fogler, Jai Anand Garg, Peng Hu, Gregory Leitus, Linda J. W. Shimon, David Milstein,

Carbon dioxide utilization in catalysis

Abstract Metal–ligand cooperation (MLC) plays an important role in catalysis. Systems reported so far are generally based on a single mode of MLC. We report here a system with potential for MLC by both amine–amide and aromatization–dearomatization ligand transformations, based on a new class of phosphino–pyridyl ruthenium pincer complexes, bearing sec ‐amine coordination. These pincer complexes are effective catalysts under unprecedented mild conditions for acceptorless dehydrogenative coupling of alcohols to esters at 35 °C and hydrogenation of esters at room temperature and 5 atm H 2 . The likely actual catalyst, a novel, crystallographically characterized monoanionic de‐aromatized enamido–Ru II complex, was obtained by deprotonation of both the NH and the methylene proton of the N‐arm of the pincer ligand.