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BIBTEX RIS

A Short Copper-Copper Distance in a (μ-1,2-Peroxo)dicopper(II) Complex Having a 1,8-Naphthyridine Unit as an Additional Bridge

2001; Wiley; Volume: 40; Issue: 8 Linguagem: Inglês

10.1002/1521-3773(20010417)40

ISSN

1521-3773

Autores

Chuan He, Jennifer L. DuBois, Britt Hedman, Keith O. Hodgson, Stephen J. Lippard,

Tópico(s)

Porphyrin and Phthalocyanine Chemistry

Resumo

A copper–copper separation of about 2.84 Å is determined by extended X-ray absorption fine structure studies for the (μ-1,2-peroxo)dicopper(II) species 1, which has only a 1,8-naphthyridine unit as an additional bridge. Complex 1 was prepared by the reaction of O2 with a dicopper(I) complex formed from BPMAN (see picture).

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