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The Geometric and Electronic Structure of a One‐Electron‐Oxidized Nickel(II) Bis(salicylidene)diamine Complex

2007; Wiley; Volume: 46; Issue: 27 Linguagem: Inglês

10.1002/anie.200701194

1521-3773

Tim Storr, Erik C. Wasinger, Russell C. Pratt, T. Daniel P. Stack,

Organometallic Complex Synthesis and Catalysis

Class III delocalization? The isolation and analysis of the ligand-radical title complex has allowed description of the changes in bonding from the reduced form as well as the extent of delocalization. The intense low-energy absorption of the oxidized complex can be described as a ligand-radical transition of a highly delocalized class III mixed-valence compound. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z701194_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.