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BIBTEX RIS

The[NH3Cl]+ Ion

2004; Wiley; Volume: 43; Issue: 39 Linguagem: Inglês

10.1002/anie.200460544

ISSN

1521-3773

Autores

Stefan Schneider, Ralf Haiges, Thorsten Schroer, Jerry A. Boatz, Karl O. Christe,

Tópico(s)

Advanced Chemical Physics Studies

Resumo

Stable! The first stable salts containing a simple, inorganic cation with an NCl bond are prepared (see picture). They are [NH3Cl]+[BF4]−, [NH3Cl]+[AsF6]−, and [NH3Cl]+[SbF6]− and can be safely prepared from (Me3Si)2NCl in mixtures of HF and the corresponding Lewis acids and could be used as storable generators for monochloramine gas.

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