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Two‐Dimensional Triangular and Square Heterometallic Clusters: Influence of the Closed‐Shell d 10 Electronic Configuration

2009; Wiley; Volume: 48; Issue: 51 Linguagem: Inglês

10.1002/anie.200903895

1521-3773

Sabrina Sculfort, P. Croizat, Abdelatif Messaoudi, Marc Bénard, Marie‐Madeleine Rohmer, R. Welter, Pierre Braunstein,

Inorganic Fluorides and Related Compounds

Angewandte Chemie International EditionVolume 48, Issue 51 p. 9663-9667 Communication Two-Dimensional Triangular and Square Heterometallic Clusters: Influence of the Closed-Shell d10 Electronic Configuration† Sabrina Sculfort, Sabrina Sculfort Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg (France), Fax: (+33) 3-6885-1322Search for more papers by this authorPierre Croizat, Pierre Croizat Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg (France), Fax: (+33) 3-6885-1322Search for more papers by this authorAbdelatif Messaoudi, Abdelatif Messaoudi Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg (France), Fax: (+33) 3-6885-1322Search for more papers by this authorMarc Bénard Dr., Marc Bénard Dr. benard@chimie.u-strasbg.fr Laboratoire de Chimie Quantique, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg (France)Search for more papers by this authorMarie-Madeleine Rohmer Dr., Marie-Madeleine Rohmer Dr. Laboratoire de Chimie Quantique, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg (France)Search for more papers by this authorRichard Welter Prof., Richard Welter Prof. Laboratoire DECOMET, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg (France)Search for more papers by this authorPierre Braunstein Dr., Pierre Braunstein Dr. braunstein@chimie.u-strasbg.fr Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg (France), Fax: (+33) 3-6885-1322Search for more papers by this author Sabrina Sculfort, Sabrina Sculfort Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg (France), Fax: (+33) 3-6885-1322Search for more papers by this authorPierre Croizat, Pierre Croizat Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg (France), Fax: (+33) 3-6885-1322Search for more papers by this authorAbdelatif Messaoudi, Abdelatif Messaoudi Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg (France), Fax: (+33) 3-6885-1322Search for more papers by this authorMarc Bénard Dr., Marc Bénard Dr. benard@chimie.u-strasbg.fr Laboratoire de Chimie Quantique, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg (France)Search for more papers by this authorMarie-Madeleine Rohmer Dr., Marie-Madeleine Rohmer Dr. Laboratoire de Chimie Quantique, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg (France)Search for more papers by this authorRichard Welter Prof., Richard Welter Prof. Laboratoire DECOMET, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg (France)Search for more papers by this authorPierre Braunstein Dr., Pierre Braunstein Dr. braunstein@chimie.u-strasbg.fr Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg (France), Fax: (+33) 3-6885-1322Search for more papers by this author First published: 08 December 2009 https://doi.org/10.1002/anie.200903895Citations: 37 † Support from the CNRS, the Ministère de l’Enseignement Supérieur et de la Recherche, the DFH/UFA, the DFG International Research Training Group GRK532, the IDRIS and CINES computer centers, and the Agence Nationale de la Recherche (ANR-06-BLAN-410) is gratefully acknowledged. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Gilded rafts: Oligomeric 2D raft clusters {M[m]}n (M=Cu, n=3; M=Ag or Au, n=4; see picture) with the same bridging metalloligand [m]={CpMo(CO)3} were prepared and structurally characterized. The ν2-triangular (M=Cu) or ν2-square (M=Ag, Au) structures of their metal–metal-bonded cores allow comparative evaluation of the d10⋅⋅⋅d10 interactions, and theoretical calculations point to a favorable contribution of diagonal Au⋅⋅⋅Au or Ag⋅⋅⋅Ag interactions. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_200903895_sm_miscellaneous_information.pdf2.5 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume48, Issue51December 14, 2009Pages 9663-9667 RelatedInformation