Hydrogen Bonds around M(μ‐O) 2 M Rhombs: Stabilizing a {Co III (μ‐O) 2 Co III } Complex at Room Temperature
2003; Wiley; Volume: 42; Issue: 1 Linguagem: Inglês
10.1002/anie.200390060
ISSN1521-3773
AutoresP.L. Larsen, T.J. Parolin, Douglas R. Powell, Michael P. Hendrich, A. S. Borovik,
Tópico(s)Magnetism in coordination complexes
ResumoHydrogen bonds to metal complexes located within the active sites of proteins have been implicated in the regulation of function. Incorporation of these noncovalent interactions into a synthetic system with bridging oxo ligands is reported. Unprecedented thermal stability of a complex with a {CoIII(μ-O)2CoIII} core is observed (see picture), in which intramolecular hydrogen bonds to the oxo ligands are present. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2003/z19547_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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