Portal de Periódicos da CAPES

Platinum‐Catalyzed Intramolecular [4C+3C] Cycloaddition between Dienes and Allenes

2007; Wiley; Volume: 47; Issue: 5 Linguagem: Inglês

10.1002/anie.200704566

1521-3773

Beatriz Trillo, Fernando López, Moisés Gulı́as, Luís Castedo, José L. Mascareñas,

Cyclopropane Reaction Mechanisms

Crossing the seven C's: The three carbon atoms of several allenyl fragments can be incorporated into seven-membered carbocycles by means of a Pt-catalyzed intramolecular [4C+3C] cycloaddition with dienes (see scheme). The transformation provides a straightforward and atom-economical entry to a variety of cycloheptane-containing polycycles from readily available acyclic precursors. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z704566_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.