Copper‐Catalyzed Trifluoromethylation of N , N ‐Dialkylhydrazones
2013; Wiley; Volume: 52; Issue: 20 Linguagem: Inglês
10.1002/anie.201300782
ISSN1521-3773
AutoresEtienne Pair, Nuno Monteiro, Didier Bouyssi, Olivier Baudoin,
Tópico(s)Inorganic Fluorides and Related Compounds
ResumoAngewandte Chemie International EditionVolume 52, Issue 20 p. 5346-5349 Communication Copper-Catalyzed Trifluoromethylation of N,N-Dialkylhydrazones Etienne Pair, Etienne Pair Université Claude Bernard Lyon 1, CNRS UMR 5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne (France) http://cosmo.univ-lyon1.fr/Index.htmlSearch for more papers by this authorDr. Nuno Monteiro, Dr. Nuno Monteiro Université Claude Bernard Lyon 1, CNRS UMR 5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne (France) http://cosmo.univ-lyon1.fr/Index.htmlSearch for more papers by this authorDr. Didier Bouyssi, Corresponding Author Dr. Didier Bouyssi [email protected] Université Claude Bernard Lyon 1, CNRS UMR 5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne (France) http://cosmo.univ-lyon1.fr/Index.htmlUniversité Claude Bernard Lyon 1, CNRS UMR 5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne (France) http://cosmo.univ-lyon1.fr/Index.htmlSearch for more papers by this authorProf. Dr. Olivier Baudoin, Corresponding Author Prof. Dr. Olivier Baudoin [email protected] Université Claude Bernard Lyon 1, CNRS UMR 5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne (France) http://cosmo.univ-lyon1.fr/Index.htmlUniversité Claude Bernard Lyon 1, CNRS UMR 5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne (France) http://cosmo.univ-lyon1.fr/Index.htmlSearch for more papers by this author Etienne Pair, Etienne Pair Université Claude Bernard Lyon 1, CNRS UMR 5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne (France) http://cosmo.univ-lyon1.fr/Index.htmlSearch for more papers by this authorDr. Nuno Monteiro, Dr. Nuno Monteiro Université Claude Bernard Lyon 1, CNRS UMR 5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne (France) http://cosmo.univ-lyon1.fr/Index.htmlSearch for more papers by this authorDr. Didier Bouyssi, Corresponding Author Dr. Didier Bouyssi [email protected] Université Claude Bernard Lyon 1, CNRS UMR 5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne (France) http://cosmo.univ-lyon1.fr/Index.htmlUniversité Claude Bernard Lyon 1, CNRS UMR 5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne (France) http://cosmo.univ-lyon1.fr/Index.htmlSearch for more papers by this authorProf. Dr. Olivier Baudoin, Corresponding Author Prof. Dr. Olivier Baudoin [email protected] Université Claude Bernard Lyon 1, CNRS UMR 5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne (France) http://cosmo.univ-lyon1.fr/Index.htmlUniversité Claude Bernard Lyon 1, CNRS UMR 5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne (France) http://cosmo.univ-lyon1.fr/Index.htmlSearch for more papers by this author First published: 08 April 2013 https://doi.org/10.1002/anie.201300782Citations: 95Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Mild and practical: Trifluoromethylation of (hetero)aromatic aldehyde N,N-dialkylhydrazones was achieved at room temperature by using Togni's trifluoromethylation reagent under CuCl catalysis (see scheme). This simple reaction is believed to occur by a CF3-radical-transfer mechanism and yields useful trifluoromethylated building blocks. Citing Literature Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description anie_201300782_sm_miscellaneous_information.pdf1.8 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume52, Issue20May 10, 2013Pages 5346-5349 RelatedInformation
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