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Artigo Revisado por pares
BIBTEX RIS

Towards Enantioselective Nucleophilic Trifluoromethylation

2004; Wiley; Volume: 11; Issue: 3 Linguagem: Inglês

10.1002/chem.200400777

ISSN

1521-3765

Autores

Solveig Roussel, Thierry Billard, Bernard R. Langlois, Laurent Saint‐James,

Tópico(s)

Carbohydrate Chemistry and Synthesis

Resumo

Abstract Various trifluoroacetamides and trifluoromethanesulfinamides, derived from chiral silylated amino alcohols, have been synthesized with the goal of achieving enantioselective nucleophilic trifluoromethylation. The best results were obtained with ( R )‐phenylglycinol derivatives, but the ee values did not exceed 30 %.

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