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Synthesis of half-titanocenes containing 1,3-imidazolidin-2-iminato ligands of type, Cp*TiCl 2 [1,3-R 2 (CH 2 N) 2 CN]: highly active catalyst precursors in ethylene (co)polymerisation

2015; Royal Society of Chemistry; Volume: 5; Issue: 79 Linguagem: Inglês

10.1039/c5ra11402k

2046-2069

Kotohiro Nomura, Srisuda Patamma, Hideshi Matsuda, Shohei Katao, Ken Tsutsumi, Hiroya Fukuda,

Carbon dioxide utilization in catalysis

Cp*TiCl 2 [1,3-(2,6-Me 2 C 6 H 3 ) 2 (CH 2 N) 2 CN] showed remarkable catalytic activities for ethylene/1-hexene copolymerisation with efficient comonomer incorporation (ex. activity 1 750 000 kg-polymer per mol-Ti per h).