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A recyclable catalyst for asymmetric transfer hydrogenation with a formic acid–triethylamine mixture in ionic liquid

2005; Royal Society of Chemistry; Issue: 16 Linguagem: Inglês

10.1039/b500320b

1364-548X

Ikuo Kawasaki, Kazuya Tsunoda, Tomoko Tsuji, Tomoko Yamaguchi, Hiroki Shibuta, Nozomi Uchida, Masayuki Yamashita, Shunsaku Ohta,

Carbon dioxide utilization in catalysis

A novel task-specific ionic ligand with an imidazolium salt moiety was synthesized, and its catalytic ability and recyclability for asymmetric transfer hydrogenation of acetophenone derivatives with a formic acid–triethylamine azeotropic mixture in an ionic liquid [bmim][PF6] was examined.