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Synthesis and characterization of porphyrin sensitizers with various electron-donating substituents for highly efficient dye-sensitized solar cells

2009; Royal Society of Chemistry; Volume: 20; Issue: 6 Linguagem: Inglês

10.1039/b919645e

1364-5501

Chou-Pou Hsieh, Hsueh‐Pei Lu, Chien‐Lan Chiu, Cheng‐Wei Lee, Shu‐Han Chuang, Chi‐Lun Mai, Wei‐Nan Yen, Shun‐Ju Hsu, Eric Wei‐Guang Diau, Chen‐Yu Yeh,

Advanced Photocatalysis Techniques

A series of porphyrin dyes with an electron-donating group (EDG) attached at a meso-position (YD1–YD8) have been designed and synthesized for use as sensitizers in dye-sensitized solar cells (DSSC). The nature of the EDG exerts a significant influence on the spectral, electrochemical and photovoltaic properties of these sensitizers. Absorption spectra of porphyrins having an amino group show broadened Soret band and red-shifted Q bands with respect to those of reference porphyrin YD0. This phenomenon is more pronounced for porphyrins YD7 and YD8 that have a π-conjugated triphenylamine at the meso-position opposite the anchoring group. Upon introduction of an EDG at the meso-position, the potential for the first oxidation alters significantly to the negative whereas that for the first reduction changes inappreciably, indicating a decreased HOMO-LUMO gap. Results of density-functional theory (DFT) calculations support the spectroelectrochemical data for a delocalization of charge between the porphyrin ring and the amino group in the first oxidative state of diarylamino-substituted porphyrins YD1–YD4, which exhibit superior photovoltaic performance among all porphyrins under investigation. With long-chain alkyl groups on the diarylamino substituent, YD2 shows the best cell performance with JSC = 13.4 mA cm−2, VOC = 0.71 V, and FF = 0.69, giving an overall efficiency 6.6% of power conversion under simulated one-sun AM1.5 illumination.