Highly regio - and diastereoselective synthesis of epoxy alcohols directly from vinyl silanes by photo-oxygenation and titanium-catalyzed oxygen transfer
1992; Elsevier BV; Volume: 33; Issue: 24 Linguagem: Inglês
10.1016/s0040-4039(00)92663-7
ISSN1873-3581
AutoresWaldemar Adam, Markus Richter,
Tópico(s)Catalytic C–H Functionalization Methods
ResumoThe photooxygenation of vinyl silanes 1 in the presence of Ti(OiPr)4 afforded regio- and diastereo-selectively the epoxy alcohols 3. Reaction of the vinyl silanes 1 with 1O2 and Ti(OiPr)4 afforded the hydroxy epoxy silanes 3 regio- and diastereoselectively.
Referência(s)