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BIBTEX RIS

Experimental and theoretical evidence of the first Au( i )⋯Bi( iii ) interaction

2006; Royal Society of Chemistry; Issue: 6 Linguagem: Inglês

10.1039/b613365g

ISSN

1364-548X

Autores

Eduardo J. Fernández, Antonio Laguna, José M. López‐de‐Luzuriaga, Miguel Monge, M. Nema, M. Elena Olmos, Javier Pérez, Cristian Silvestru,

Tópico(s)

Inorganic Fluorides and Related Compounds

Resumo

Complex [Au(C6F5)2][Bi(C6H4CH2NMe2-2)2] 1 displays the first example of an interaction between Au(I) and Bi(III), the nature of which is shown to be consistent with the presence of a high ionic contribution (79%) and a dispersion type (van der Waals) interaction (21%).

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