Quasi-Elastic Neutron Scattering Study of NH 4 Dynamics in K 1− x (NH 4 ) x H 2 PO 4 Mixed Crystals
1993; Institute of Physics; Volume: 22; Issue: 9 Linguagem: Inglês
10.1209/0295-5075/22/9/011
ISSN1286-4854
AutoresΑ. V. Belushkin, C.J. Carlile, L. A. Shuvalov,
Tópico(s)Advanced NMR Techniques and Applications
ResumoThe dynamics of NH4 groups in K1−x(NH4)xH2PO4 mixed crystals have been studied using quasi-elastic neutron scattering on powders for x = 0.6 and 0.9. It was found that the rotational dynamics of NH4 is quite different of these two concentrations. In the sample with x = 0.9, which undergoes a strongly first-order phase transition into an antiferroelectric phase, the activation energy for NH4 reorientations was found to be 130 meV. The elastic incoherent structure factor (EISF), which is a measure of the time-averaged spatial distribution of protons in the lattice, was temperature independent. In contrast, the sample with x = 0.6 forms a dipolar glass state at low temperatures and the activation energy for NH4 reorientations is found to be considerably lower (74 meV). The EISF for the lower concentration sample is strongly temperature dependent. The data obtained are discussed on the basis of mechanisms of glass formation.
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