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Rational Design of a Coordination Cage with a Trigonal‐Bipyramidal Shape Constructed from 33 Building Units

2005; Wiley; Volume: 44; Issue: 19 Linguagem: Inglês

10.1002/anie.200463034

1521-3773

I. Müller, Daniela Möller,

Magnetism in coordination complexes

According to plan: C2- and C3-symmetric ligands are essential to the rational design of a low-symmetry coordination cage with the outer shape of a trigonal bipyramid (view along the C3 axis shown; green: Pd, red: ligand, blue: 5,5-diethylbarbiturate). The characterization of an intermediate gives insight to the mechanism of formation. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z463034_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.