A Planar {Mn 19 (OH) 12 } 26+ Unit Incorporated in a 60‐Tungsto‐6‐Silicate Polyanion
2011; Wiley; Volume: 50; Issue: 26 Linguagem: Inglês
10.1002/anie.201007617
ISSN1521-3773
AutoresBassem S. Bassil, Masooma Ibrahim, Rami Al‐Oweini, Marie Asano, Zhenxing Wang, Johan van Tol, Naresh S. Dalal, Kwang‐Yong Choi, Rosa Ngo Biboum, Bineta Keita, Louis Nadjo, Ulrich Kortz,
Tópico(s)Metal-Organic Frameworks: Synthesis and Applications
ResumoAngewandte Chemie International EditionVolume 50, Issue 26 p. 5961-5964 Communication A Planar {Mn19(OH)12}26+ Unit Incorporated in a 60-Tungsto-6-Silicate Polyanion† Dr. Bassem S. Bassil, Dr. Bassem S. Bassil Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229 http://www.jacobs-university.de/ses/ukortz These authors contributed equally to this work.Search for more papers by this authorMasooma Ibrahim, Masooma Ibrahim Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229 http://www.jacobs-university.de/ses/ukortz These authors contributed equally to this work.Search for more papers by this authorRami Al-Oweini, Rami Al-Oweini Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229 http://www.jacobs-university.de/ses/ukortzSearch for more papers by this authorMarie Asano, Marie Asano Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229 http://www.jacobs-university.de/ses/ukortzSearch for more papers by this authorZhenxing Wang, Zhenxing Wang Department of Chemistry and Biochemistry, National High Magnetic Field Laboratory, Florida State University, Tallahassee, FL 32306 (USA)Search for more papers by this authorDr. Johan van Tol, Dr. Johan van Tol Department of Chemistry and Biochemistry, National High Magnetic Field Laboratory, Florida State University, Tallahassee, FL 32306 (USA)Search for more papers by this authorProf. Naresh S. Dalal, Corresponding Author Prof. Naresh S. Dalal dalal@chem.fsu.edu Department of Chemistry and Biochemistry, National High Magnetic Field Laboratory, Florida State University, Tallahassee, FL 32306 (USA) Naresh S. Dalal, Department of Chemistry and Biochemistry, National High Magnetic Field Laboratory, Florida State University, Tallahassee, FL 32306 (USA) Ulrich Kortz, Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229 http://www.jacobs-university.de/ses/ukortzSearch for more papers by this authorProf. Kwang-Yong Choi, Prof. Kwang-Yong Choi Department of Physics, Chung-Ang University, Seoul 156-756 (Republic of Korea)Search for more papers by this authorRosa Ngo Biboum, Rosa Ngo Biboum Laboratoire de Chimie Physique, Université Paris-Sud 11, 91405 Orsay Cedex (France)Search for more papers by this authorDr. Bineta Keita, Dr. Bineta Keita Laboratoire de Chimie Physique, Université Paris-Sud 11, 91405 Orsay Cedex (France)Search for more papers by this authorProf. Louis Nadjo, Prof. Louis Nadjo Laboratoire de Chimie Physique, Université Paris-Sud 11, 91405 Orsay Cedex (France)Search for more papers by this authorProf. Ulrich Kortz, Corresponding Author Prof. Ulrich Kortz u.kortz@jacobs-university.de Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229 http://www.jacobs-university.de/ses/ukortz Naresh S. Dalal, Department of Chemistry and Biochemistry, National High Magnetic Field Laboratory, Florida State University, Tallahassee, FL 32306 (USA) Ulrich Kortz, Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229 http://www.jacobs-university.de/ses/ukortzSearch for more papers by this author Dr. Bassem S. Bassil, Dr. Bassem S. Bassil Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229 http://www.jacobs-university.de/ses/ukortz These authors contributed equally to this work.Search for more papers by this authorMasooma Ibrahim, Masooma Ibrahim Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229 http://www.jacobs-university.de/ses/ukortz These authors contributed equally to this work.Search for more papers by this authorRami Al-Oweini, Rami Al-Oweini Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229 http://www.jacobs-university.de/ses/ukortzSearch for more papers by this authorMarie Asano, Marie Asano Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229 http://www.jacobs-university.de/ses/ukortzSearch for more papers by this authorZhenxing Wang, Zhenxing Wang Department of Chemistry and Biochemistry, National High Magnetic Field Laboratory, Florida State University, Tallahassee, FL 32306 (USA)Search for more papers by this authorDr. Johan van Tol, Dr. Johan van Tol Department of Chemistry and Biochemistry, National High Magnetic Field Laboratory, Florida State University, Tallahassee, FL 32306 (USA)Search for more papers by this authorProf. Naresh S. Dalal, Corresponding Author Prof. Naresh S. Dalal dalal@chem.fsu.edu Department of Chemistry and Biochemistry, National High Magnetic Field Laboratory, Florida State University, Tallahassee, FL 32306 (USA) Naresh S. Dalal, Department of Chemistry and Biochemistry, National High Magnetic Field Laboratory, Florida State University, Tallahassee, FL 32306 (USA) Ulrich Kortz, Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229 http://www.jacobs-university.de/ses/ukortzSearch for more papers by this authorProf. Kwang-Yong Choi, Prof. Kwang-Yong Choi Department of Physics, Chung-Ang University, Seoul 156-756 (Republic of Korea)Search for more papers by this authorRosa Ngo Biboum, Rosa Ngo Biboum Laboratoire de Chimie Physique, Université Paris-Sud 11, 91405 Orsay Cedex (France)Search for more papers by this authorDr. Bineta Keita, Dr. Bineta Keita Laboratoire de Chimie Physique, Université Paris-Sud 11, 91405 Orsay Cedex (France)Search for more papers by this authorProf. Louis Nadjo, Prof. Louis Nadjo Laboratoire de Chimie Physique, Université Paris-Sud 11, 91405 Orsay Cedex (France)Search for more papers by this authorProf. Ulrich Kortz, Corresponding Author Prof. Ulrich Kortz u.kortz@jacobs-university.de Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229 http://www.jacobs-university.de/ses/ukortz Naresh S. Dalal, Department of Chemistry and Biochemistry, National High Magnetic Field Laboratory, Florida State University, Tallahassee, FL 32306 (USA) Ulrich Kortz, Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229 http://www.jacobs-university.de/ses/ukortzSearch for more papers by this author First published: 17 May 2011 https://doi.org/10.1002/anie.201007617Citations: 164 † U.K. thanks the German Science Foundation (DFG-KO-2288/3-2), Jacobs University and the Fonds der Chemischen Industrie for research support. M.I. thanks DAAD and the Higher Education Commission of Pakistan for a doctoral fellowship, and the University of Balochistan, Quetta, Pakistan for allowing her to pursue PhD studies at Jacobs University (Germany). NHMFL is supported by the State of Florida and the NSF Cooperative agreement No. DMR 0654118. K.-Y. C. acknowledges financial support from Korea NRF (Grant No. 2009-0093817). Figure 1 was generated by Diamond Version 3.2c (copyright Crystal Impact GbR). Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Manganese in large numbers: The largest number of manganese ions ever incorporated in a polyoxometalate (POM) is found in a planar Mn19-oxo-hydroxo magnetic cluster incorporated in a discrete 60-tungsto-6-silicate (see structure Mn yellow, O red/pink). The compound has interesting structural, magnetic, and electrochemical properties. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201007617_sm_miscellaneous_information.pdf1.4 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume50, Issue26June 20, 2011Pages 5961-5964 RelatedInformation
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