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One‐Step Synthesis of the Benzocyclo[penta‐ to octa‐]isoindole Core

2009; Wiley; Volume: 48; Issue: 30 Linguagem: Inglês

10.1002/anie.200901246

1521-3773

Yimin Hu, Chenli Yu, Dong Ren, Qiong Hu, Lidong Zhang, Dong Cheng,

Synthetic Organic Chemistry Methods

Angewandte Chemie International EditionVolume 48, Issue 30 p. 5448-5451 Communication One-Step Synthesis of the Benzocyclo[penta- to octa-]isoindole Core† Yimin Hu Prof. Dr., Yimin Hu Prof. Dr. [email protected] Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Key Laboratory of Functional Molecular-Based Materials, Institute of Organic Chemistry, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000 (China), Fax: (+86) 553-388-3517Search for more papers by this authorChenli Yu, Chenli Yu Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Key Laboratory of Functional Molecular-Based Materials, Institute of Organic Chemistry, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000 (China), Fax: (+86) 553-388-3517Search for more papers by this authorDong Ren, Dong Ren Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Key Laboratory of Functional Molecular-Based Materials, Institute of Organic Chemistry, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000 (China), Fax: (+86) 553-388-3517Search for more papers by this authorQiong Hu, Qiong Hu Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Key Laboratory of Functional Molecular-Based Materials, Institute of Organic Chemistry, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000 (China), Fax: (+86) 553-388-3517Search for more papers by this authorLidong Zhang, Lidong Zhang Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Key Laboratory of Functional Molecular-Based Materials, Institute of Organic Chemistry, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000 (China), Fax: (+86) 553-388-3517Search for more papers by this authorDong Cheng, Dong Cheng Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Key Laboratory of Functional Molecular-Based Materials, Institute of Organic Chemistry, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000 (China), Fax: (+86) 553-388-3517Search for more papers by this author Yimin Hu Prof. Dr., Yimin Hu Prof. Dr. [email protected] Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Key Laboratory of Functional Molecular-Based Materials, Institute of Organic Chemistry, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000 (China), Fax: (+86) 553-388-3517Search for more papers by this authorChenli Yu, Chenli Yu Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Key Laboratory of Functional Molecular-Based Materials, Institute of Organic Chemistry, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000 (China), Fax: (+86) 553-388-3517Search for more papers by this authorDong Ren, Dong Ren Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Key Laboratory of Functional Molecular-Based Materials, Institute of Organic Chemistry, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000 (China), Fax: (+86) 553-388-3517Search for more papers by this authorQiong Hu, Qiong Hu Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Key Laboratory of Functional Molecular-Based Materials, Institute of Organic Chemistry, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000 (China), Fax: (+86) 553-388-3517Search for more papers by this authorLidong Zhang, Lidong Zhang Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Key Laboratory of Functional Molecular-Based Materials, Institute of Organic Chemistry, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000 (China), Fax: (+86) 553-388-3517Search for more papers by this authorDong Cheng, Dong Cheng Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Key Laboratory of Functional Molecular-Based Materials, Institute of Organic Chemistry, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000 (China), Fax: (+86) 553-388-3517Search for more papers by this author First published: 08 July 2009 https://doi.org/10.1002/anie.200901246Citations: 60 † Support of this research by grants from the National Science Foundation of China (20872002, 20572001) and the Education Department of Anhui Province (TD200707) is gratefully acknowledged. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Three in one go: Unactivated dienes containing a cycloalkenyl moiety reacted with a range of substituted aryl halides in the presence of Pd(OAc)2/PPh3 to afford fused polycyclic heterocycles (see scheme). Three carbon–carbon bonds are formed in this domino reaction, which involves highly regioselective CC coupling and CH functionalization steps. DMF=N,N-dimethylformamide; Bn=benzyl, Ts=p-toluenesulfonyl. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_200901246_sm_miscellaneous_information.pdf839.6 KB miscellaneous information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume48, Issue30July 13, 2009Pages 5448-5451 RelatedInformation