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Metal‐Free Hydrogenation of Electron‐Poor Allenes and Alkenes

2012; Wiley; Volume: 51; Issue: 49 Linguagem: Inglês

10.1002/anie.201205348

1521-3773

Blanca Inés, David Palomas, S. Holle, Sebastian Steinberg, Juan Nicasio‐Collazo, Manuel Alcarazo,

Asymmetric Hydrogenation and Catalysis

Angewandte Chemie International EditionVolume 51, Issue 49 p. 12367-12369 Communication Metal-Free Hydrogenation of Electron-Poor Allenes and Alkenes† Dr. Blanca Inés, Dr. Blanca Inés Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorDr. David Palomas, Dr. David Palomas Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorSigrid Holle, Sigrid Holle Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorSebastian Steinberg, Sebastian Steinberg Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorJuan A. Nicasio, Juan A. Nicasio Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorDr. Manuel Alcarazo, Corresponding Author Dr. Manuel Alcarazo alcarazo@mpi-muelheim.mpg.de Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this author Dr. Blanca Inés, Dr. Blanca Inés Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorDr. David Palomas, Dr. David Palomas Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorSigrid Holle, Sigrid Holle Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorSebastian Steinberg, Sebastian Steinberg Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorJuan A. Nicasio, Juan A. Nicasio Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorDr. Manuel Alcarazo, Corresponding Author Dr. Manuel Alcarazo alcarazo@mpi-muelheim.mpg.de Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this author First published: 04 November 2012 https://doi.org/10.1002/anie.201205348Citations: 86 † Generous financial support from the Fonds der Chemischen Industrie and the European Research Council (ERC Starting grant agreement no. 277963) is gratefully acknowledged. We also thank Prof. A. Fürstner for constant encouragement and the NMR spectroscopy and X-ray crystallography departments of our institute for excellent support. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract The poorer, the better: A metal-free catalytic procedure for the reduction of electron-poor allenes and alkenes has been developed. The method employs a frustrated Lewis pair based catalyst. 1,4-Diazabicyclo[2.2.2]octane (DABCO)/B(C6F5)3 was shown to be the best combination in optimization studies. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201205348_sm_miscellaneous_information.pdf4.1 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume51, Issue49December 3, 2012Pages 12367-12369 RelatedInformation