Asymmetric Baeyer-Villiger Reaction with Hydrogen Peroxide Catalyzed by a Novel Planar-Chiral Bisflavin
2002; Wiley; Volume: 41; Issue: 13 Linguagem: Inglês
10.1002/1521-3773(20020703)41
ISSN1521-3773
AutoresShun‐Ichi Murahashi, Satoshi Ono, Yasushi Imada,
Tópico(s)Catalysis for Biomass Conversion
ResumoThe chiral organocatalyst bisflavin 1 catalyzes the asymmetric Baeyer–Villiger reaction of cyclobutanones with H2O2 (see scheme). The corresponding lactones are obtained with up to 74 % ee.
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