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Synthesis and Characterization of the Metal(I) Dimers [Ar′MMAr′]: Comparisons with Quintuple‐Bonded [Ar′CrCrAr′]

2008; Wiley; Volume: 47; Issue: 47 Linguagem: Inglês

10.1002/anie.200802657

1521-3773

Tailuan Nguyen, W.A. Merrill, Chengbao Ni, Hao Lei, James C. Fettinger, Bobby D. Ellis, Gary J. Long, M. Brynda, Philip P. Power,

Inorganic Chemistry and Materials

Angewandte Chemie International EditionVolume 47, Issue 47 p. 9115-9117 Communication Synthesis and Characterization of the Metal(I) Dimers [Ar′MMAr′]: Comparisons with Quintuple-Bonded [Ar′CrCrAr′]† Tailuan Nguyen, Tailuan Nguyen Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this authorW. Alexander Merrill, W. Alexander Merrill Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this authorChengbao Ni, Chengbao Ni Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this authorHao Lei, Hao Lei Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this authorJames C. Fettinger Dr., James C. Fettinger Dr. Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this authorBobby D. Ellis Dr., Bobby D. Ellis Dr. Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this authorGary J. Long Prof., Gary J. Long Prof. Department of Chemistry, Missouri University of Science and Technology (USA)Search for more papers by this authorMarcin Brynda Dr., Marcin Brynda Dr. Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this authorPhilip P. Power Prof., Philip P. Power Prof. pppower@ucdavis.edu Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this author Tailuan Nguyen, Tailuan Nguyen Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this authorW. Alexander Merrill, W. Alexander Merrill Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this authorChengbao Ni, Chengbao Ni Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this authorHao Lei, Hao Lei Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this authorJames C. Fettinger Dr., James C. Fettinger Dr. Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this authorBobby D. Ellis Dr., Bobby D. Ellis Dr. Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this authorGary J. Long Prof., Gary J. Long Prof. Department of Chemistry, Missouri University of Science and Technology (USA)Search for more papers by this authorMarcin Brynda Dr., Marcin Brynda Dr. Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this authorPhilip P. Power Prof., Philip P. Power Prof. pppower@ucdavis.edu Department of Chemistry, University of California, Davis, One Shields Avenue, CA, 95616 (USA), Fax: (+1) 530-752-8995Search for more papers by this author First published: 05 November 2008 https://doi.org/10.1002/anie.200802657Citations: 63 † We are grateful to the National Science Foundation (CHE-0641020) for financial support. B.D.E. thanks the NSERC of Canada for a postdoctoral fellowship. Ar′=C6H3-2,6-(2,6-iPr2C6H3)2; M=Fe or Co. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Cobalt together: The iron and cobalt analogues of the quintuple-bonded chromium species [Ar′CrCrAr′] (Ar′=C6H3-2,6-(2,6-iPr2C6H3)2) are described and their structures investigated by crystallography, magnetic studies, and density functional calculations. Metal-η6-aryl interactions in [Ar′FeFeAr′] and [Ar′CoCoAr′] are stronger than those detected in [Ar′CrCrAr′], whereas metal–metal bonding is much weaker. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_200802657_sm_miscellaneous_information.pdf273.2 KB miscellaneous information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume47, Issue47November 10, 2008Pages 9115-9117 RelatedInformation