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Artigo Revisado por pares
BIBTEX RIS

A Water‐Complexed Organolithium Compound: [LiCH(CN) 2 · H 2 O · TMEDA] ∞

1992; Wiley; Volume: 31; Issue: 1 Linguagem: Inglês

10.1002/anie.199200771

ISSN

1521-3773

Autores

Christoph Lambert, Paul von Ragué Schleyer, Ursula Pieper, Dietmar Stalke,

Tópico(s)

Chemical Reaction Mechanisms

Resumo

Not the bidentate amine ligand, but water coordinates to the Li cation in [LiCH(CN) 2 · H 2 O · TMEDA] ∞ 1 (TMEDA = tetramethylethylenediamine), a very unusual structural characteristic for lithiated organic compounds. Inter‐molecular hydrogen bonds between the H atoms of the aqua ligands and the N atoms of TMEDA are observed. 1 is therefore the first water‐complexed lithiated organic compound derived from a CH acid.

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