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Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

2012; Royal Society of Chemistry; Volume: 41; Issue: 18 Linguagem: Inglês

10.1039/c2dt30174a

1477-9234

Adam F. Gross, Elena Sherman, John J. Vajo,

Covalent Organic Framework Applications

Sodalite zeolitic imidazolate frameworks containing Co (ZIF-67) and Zn (ZIF-8) were synthesized at room temperature under aqueous conditions in 10 min. A trialkylamine deprotonated the 2-methylimidazole ligand and nucleated the frameworks. Furthermore, the ligand acted as a structure directing agent in place of an organic solvent.