Intramolecular Aromatic Amination through Iron‐Mediated Nitrene Transfer
2003; Wiley; Volume: 42; Issue: 36 Linguagem: Inglês
10.1002/anie.200351605
ISSN1521-3773
AutoresMichael P. Jensen, M.P. Mehn, Lawrence Que,
Tópico(s)Catalytic C–H Functionalization Methods
ResumoAn iron(III) anilide complex can be formed through the reaction of phenyl-N-tosylimidoiodinane with the non-heme iron complex [(6-PhTPA)FeII(NCCH3)2](ClO4)2 (TPA= tris(2-pyridylmethyl)amine), in which an efficient transfer of the nitrene moiety to the ortho position of the α-phenyl substituent is achieved (a hypothetical structure of the complex is illustrated, in which the tolyl ring, except for the ipso carbon atom, is excluded for clarity; Fe pink, S yellow, O red, N blue).
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