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Synthesis and Resolution of BICOL, a Carbazole Analogue of BINOL

2002; Wiley; Volume: 2002; Issue: 12 Linguagem: Inglês

10.1002/1099-0690(200206)2002

1434-193X

Peter N. M. Botman, Martijn Postma, J. Fraanje, K. Goubitz, H. Schenk, Jan H. van Maarseveen, Henk Hiemstra,

Biological Activity of Diterpenoids and Biflavonoids

European Journal of Organic ChemistryVolume 2002, Issue 12 p. 1952-1955 Full Paper Synthesis and Resolution of BICOL, a Carbazole Analogue of BINOL Peter N. M. Botman, Peter N. M. Botman Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The NetherlandsSearch for more papers by this authorMartijn Postma, Martijn Postma Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The NetherlandsSearch for more papers by this authorJan Fraanje, Jan Fraanje Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The NetherlandsSearch for more papers by this authorKees Goubitz, Kees Goubitz Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The NetherlandsSearch for more papers by this authorHenk Schenk, Henk Schenk Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The NetherlandsSearch for more papers by this authorJan H. van Maarseveen, Jan H. van Maarseveen Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The NetherlandsSearch for more papers by this authorHenk Hiemstra, Henk Hiemstra Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The NetherlandsSearch for more papers by this author Peter N. M. Botman, Peter N. M. Botman Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The NetherlandsSearch for more papers by this authorMartijn Postma, Martijn Postma Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The NetherlandsSearch for more papers by this authorJan Fraanje, Jan Fraanje Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The NetherlandsSearch for more papers by this authorKees Goubitz, Kees Goubitz Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The NetherlandsSearch for more papers by this authorHenk Schenk, Henk Schenk Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The NetherlandsSearch for more papers by this authorJan H. van Maarseveen, Jan H. van Maarseveen Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The NetherlandsSearch for more papers by this authorHenk Hiemstra, Henk Hiemstra Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The NetherlandsSearch for more papers by this author First published: 24 May 2002 https://doi.org/10.1002/1099-0690(200206)2002:12 3.0.CO;2-LCitations: 16Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract The synthesis and resolution of a novel chiral C2-symmetric bicarbazolediol (BICOL), is reported. The key step in the synthesis is the copper(II)-catalysed oxidative phenol coupling of 3-hydroxycarbazole. Menthyl chloroformate is used as resolving agent for the separation of the two enantiomers of BICOL. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002) Citing Literature Volume2002, Issue12June 2002Pages 1952-1955 RelatedInformation