The mass spectra of (trimethylstannyl) x methanes: Occurrence of tin‐carbon double bonds
1975; Wiley; Volume: 10; Issue: 1 Linguagem: Inglês
10.1002/oms.1210100104
ISSN2376-3884
AutoresDonald R. Dimmel, Charles A. Wilkie, Paul J. Lamothe,
Tópico(s)Metal and Thin Film Mechanics
ResumoAbstract The mass spectra of (Me 3 Sn) n CH 4−n , where n varies from 1 to 4, (Me 3 Sn) 2 CCl X , where X equals H, Cl, Br or I, together with some tetraalkyltin compounds and Me 3 SnCCl 3 , are presented. Comparisons with mass spectra of the silicon analogs 1 show a large number of similarities, including the appearance of allylic ions which require Group IV metal to carbon π‐bonding. Multiple rearrangements are observed with the halogenated tin compounds which bring the α‐halogen into direct bonding with the tin atom.
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