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[Fe(2,4,6‐ t Bu 3 C 6 H 2 ) 2 ], a Monomeric Diaryl Complex with Two‐Coordinate Iron( II )

1995; Wiley; Volume: 34; Issue: 3 Linguagem: Inglês

10.1002/anie.199503251

1521-3773

W. Seidel, Hardy Müller, Helmar Görls,

Metalloenzymes and iron-sulfur proteins

Angewandte Chemie International Edition in EnglishVolume 34, Issue 3 p. 325-327 Communication [Fe(2,4,6-tBu3C6H2)2], a Monomeric Diaryl Complex with Two-Coordinate Iron(II)† Prof. Dr. Wolfgang Seidel, Corresponding Author Prof. Dr. Wolfgang Seidel Institut für Anorganische und Analytische Chemie der Universität, August-Bebel-Strasse 2, D-07743 Jena (Germany) Telefax: Int. code + (3641)635538Institut für Anorganische und Analytische Chemie der Universität, August-Bebel-Strasse 2, D-07743 Jena (Germany) Telefax: Int. code + (3641)635538Search for more papers by this authorDr. Hardy Müller, Dr. Hardy Müller LS Polymerchemie der Technischen Universität Chemnitz Zwickau (Germany)Search for more papers by this authorDr. Helmar Görls, Dr. Helmar Görls Max-Planck-Gesellschaft, Arbeitsgruppe CO2-Chemie an der Universität Jena (Germany)Search for more papers by this author Prof. Dr. Wolfgang Seidel, Corresponding Author Prof. Dr. Wolfgang Seidel Institut für Anorganische und Analytische Chemie der Universität, August-Bebel-Strasse 2, D-07743 Jena (Germany) Telefax: Int. code + (3641)635538Institut für Anorganische und Analytische Chemie der Universität, August-Bebel-Strasse 2, D-07743 Jena (Germany) Telefax: Int. code + (3641)635538Search for more papers by this authorDr. Hardy Müller, Dr. Hardy Müller LS Polymerchemie der Technischen Universität Chemnitz Zwickau (Germany)Search for more papers by this authorDr. Helmar Görls, Dr. Helmar Görls Max-Planck-Gesellschaft, Arbeitsgruppe CO2-Chemie an der Universität Jena (Germany)Search for more papers by this author First published: February 21, 1995 https://doi.org/10.1002/anie.199503251Citations: 49 † This work was supported by the Fonds der Chemischen Industrie. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract The surprising thermal stability of the first monomeric, homoleptic diaryliron(II) complex 1 arises because its Fe center is very well shielded by the sterically demanding ligands. The magnetic moment of 4.77 μB indicates a high-spin state of the highly soluble, air- and moisture-sensitive complex. Citing Literature Volume34, Issue3February 21, 1995Pages 325-327 RelatedInformation