Photo-induced insertion of tungsten into a methyl C–H bond in p-xylene and mesitylene: crystal structure of (η-C 5 H 5 ) 2 W[CH 2 (3,5-Me 2 C 6 H 3 )] 2

Artigo

Photo-induced insertion of tungsten into a methyl C–H bond in p-xylene and mesitylene: crystal structure of (η-C 5 H 5 ) 2 W[CH 2 (3,5-Me 2 C 6 H 3 )] 2

1974; Royal Society of Chemistry; Issue: 18 Linguagem: Inglês

10.1039/c39740000747

ISSN

2050-5639

Autores

Keith Elmitt, Malcolm L. H. Green, R. A. Forder, I. W. Jefferson, Keith Prout,

Tópico(s)

Advanced Chemical Physics Studies

Resumo

Irradiation of a mesitylene solution of the dihydride (η-CH)WH with a mercury lamp (366 nm) gives the bis-alkyl derivative (η-CH)W[CH(3,5-MeCH)]. Malcolm Green FRS: In celebration of his 80th Birthday

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Photo-induced insertion of tungsten into a methyl C–H bond in p-xylene and mesitylene: crystal structure of (η-C 5 H 5 ) 2 W[CH 2 (3,5-Me 2 C 6 H 3 )] 2