Voltar
Artigo Revisado por pares
BIBTEX RIS

Step‐by‐Step Assembly of Trivacant Tungstosilicates: Synthesis and Characterization of Tetrameric Anions

2005; Wiley; Volume: 118; Issue: 1 Linguagem: Inglês

10.1002/ange.200502441

ISSN

1521-3757

Autores

Nathalie Leclerc‐Laronze, Mohamed Haouas, Jérôme Marrot, Françis Taulelle, Gilbert Hervé,

Tópico(s)

Advanced Nanomaterials in Catalysis

Resumo

Angewandte ChemieVolume 118, Issue 1 p. 145-148 Zuschrift Step-by-Step Assembly of Trivacant Tungstosilicates: Synthesis and Characterization of Tetrameric Anions Nathalie Leclerc-Laronze Dr., Nathalie Leclerc-Laronze Dr. Institut Lavoisier, IREM UMR 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 1-39-25-43-81Search for more papers by this authorMohamed Haouas Dr., Mohamed Haouas Dr. Institut Lavoisier, IREM UMR 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 1-39-25-43-81Search for more papers by this authorJérôme Marrot Dr., Jérôme Marrot Dr. Institut Lavoisier, IREM UMR 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 1-39-25-43-81Search for more papers by this authorFrancis Taulelle Dr., Francis Taulelle Dr. Institut Lavoisier, IREM UMR 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 1-39-25-43-81Search for more papers by this authorGilbert Hervé Prof., Gilbert Hervé Prof. [email protected] Institut Lavoisier, IREM UMR 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 1-39-25-43-81Search for more papers by this author Nathalie Leclerc-Laronze Dr., Nathalie Leclerc-Laronze Dr. Institut Lavoisier, IREM UMR 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 1-39-25-43-81Search for more papers by this authorMohamed Haouas Dr., Mohamed Haouas Dr. Institut Lavoisier, IREM UMR 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 1-39-25-43-81Search for more papers by this authorJérôme Marrot Dr., Jérôme Marrot Dr. Institut Lavoisier, IREM UMR 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 1-39-25-43-81Search for more papers by this authorFrancis Taulelle Dr., Francis Taulelle Dr. Institut Lavoisier, IREM UMR 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 1-39-25-43-81Search for more papers by this authorGilbert Hervé Prof., Gilbert Hervé Prof. [email protected] Institut Lavoisier, IREM UMR 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 1-39-25-43-81Search for more papers by this author First published: 13 December 2005 https://doi.org/10.1002/ange.200502441Citations: 11Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Tungstosilicat-Bausteine: Beim Ansäuern der monomeren Spezies [SiW9O34]10− entstehen die dimeren Anionen α-[{K(H2O)2}Si2W18O66]15−. Zwei dieser Anionen können direkt (siehe Bild) oder, in Gegenwart von Kieselsäure, über einen elektrophilen [Si4O4]8+-Ring miteinander verknüpft werden. Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2006/z502441_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 1aC. du Peloux, P. Mialane, A. Dolbecq, J. Marrot, F. Sécheresse, Angew. Chem. 2002, 114, 2932–2934; 10.1002/1521-3757(20020802)114:15 3.0.CO;2-O Google ScholarAngew. Chem. Int. Ed. 2002, 41, 2808–2810; 10.1002/1521-3773(20020802)41:15 3.0.CO;2-X CASPubMedWeb of Science®Google Scholar 1bA. Müller, A. M. Todea, J. van Slageren, M. Dressel, H. Bögge, M. Schmidtmann, M. Luban, L. Engelhardt, M. Rusu, Angew. Chem. 2005, 117, 3925–3929; 10.1002/ange.200500697 Google ScholarAngew. Chem. Int. Ed. 2005, 44, 3857–3861. 10.1002/anie.200500697 CASPubMedWeb of Science®Google Scholar 2 2aA. Müller, F. Peters, M. T. Pope, D. Gatteschi, Chem. Rev. 1998, 98, 239–271; 10.1021/cr9603946 CASPubMedWeb of Science®Google Scholar 2bL. Cronin, C. Beugholt, E. Krickemeyer, M. Schmidtmann, H. Bögge, P. Kögerler, T. K. K. Luong, A. Müller, Angew. Chem. 2002, 114, 2929–2932; 10.1002/1521-3757(20020802)114:15 3.0.CO;2-L Google ScholarAngew. Chem. Int. Ed. 2002, 41, 2805–2808. 10.1002/1521-3773(20020802)41:15 3.0.CO;2-E CASPubMedWeb of Science®Google Scholar 3Examples of recent work include: Google Scholar 3aE. Cadot, M.-A. Pilette, J. Marrot, F. Sécheresse, Angew. Chem. 2003, 115, 2223–2226; 10.1002/ange.200250663 Google ScholarAngew. Chem. Int. Ed. 2003, 42, 2173–2176; 10.1002/anie.200250663 CASPubMedWeb of Science®Google Scholar 3bJ. Marrot, M.-A. Pilette, F. Sécheresse, E. Cadot, Inorg. Chem. 2003, 42, 3609–3615; 10.1021/ic026191j CASPubMedWeb of Science®Google Scholar 3cS. S. Mal, U. Kortz, Angew. Chem. 2005, 117, 3843–3846; 10.1002/ange.200500682 Google ScholarAngew. Chem. Int. Ed. 2005, 44, 3777–3780; 10.1002/anie.200500682 CASPubMedWeb of Science®Google Scholar 3dU. Kortz, F. Hussain, M. Reicke, Angew. Chem. 2005, 117, 3839–3843; 10.1002/ange.200500548 Google ScholarAngew. Chem. Int. Ed. 2005, 44, 3773–3777. 10.1002/anie.200500548 CASPubMedWeb of Science®Google Scholar 4N. Laronze, J. Marrot, G. Hervé, Chem. Commun. 2003, 2360–2361. 10.1039/B307276B CASPubMedWeb of Science®Google Scholar 5 5aN. Leclerc-Laronze, J. Marrot, G. Hervé, Inorg. Chem. 2005, 44, 1275–1281; 10.1021/ic0486769 CASPubMedWeb of Science®Google Scholar 5bL.-H. Bi, U. Kortz, Inorg. Chem. 2004, 43, 7961–7962. 10.1021/ic048689m CASPubMedWeb of Science®Google Scholar 6Crystals of 1 and 2 were mounted in a Lindemann tube. X-ray intensity data were collected on a Bruker X8-APEX2 CCD area-detector diffractometer by using MoKα radiation (λ=0.71073 Å). Seven sets of narrow data frames (60 s per frame for 1 and 30 s for 2) were collected at different values of θ (for 5 and 2 initial values of ϕ and ω, respectively for 1; for 3 and 4 initial values of ϕ and ω, respectively for 2) by using 0.5° increments of ϕ or ω. Crystal data and structure refinements: 1: colorless crystal, 0.28×0.26×0.20 mm3, triclinic, space group P (no. 2), a=18.7555(5), b=22.5419(5), c=23.7793(6) Å, α=112.543(1), β=96.996(1), γ=104.136(1)°, V=8739.8(4) Å3, Z=2, ρcalcd=3.833 g cm−3, μ(MoKα)=24.012 mm−1, F(000)=8782, T=296(2) K. A total of 69 677 independent reflections, 44 418 observed with I>2σ(I), R(int)=0.057, R1=0.0492, wR2=0.1224, 2177 refined parameters. 2: colorless crystal, 0.26×0.14×0.08 mm3, triclinic, space group P (no. 2), a=18.5206(7), b=20.9506(7), c=24.5669(9) Å, α=91.972(2), β=104.569(2), γ=96.615(2)°, V=9144.5(6) Å3, Z=2, ρcalcd=3.836 g cm−3, μ(MoKα)=23.141 mm−1, F(000)=9250, T=296(2) K. A total of 100 269 independent reflections, 48 690 observed with I > 2σ(I), R(int)=0.0841, R1=0.0547, wR2=0.1242, 2206 refined parameters. Data reduction was accomplished by using SAINT V7.03. The substantial redundancy in data allowed a semiempirical absorption correction (SADABS V2.10) to be applied, on the basis of multiple measurements of equivalent reflections. The structure was solved by direct methods, developed by successive difference Fourier syntheses, and refined by full-matrix least-squares on all F 2 data with SHELXTL V6.12. Further details on the crystal-structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany (fax: (+49) 7247-808-666; e-mail: [email protected]), on quoting the depository number CSD 415593. Google Scholar 7N. E. Brese, M. O'Keeffe, Acta Crystallogr. Sect. A 1991, 47, 192–197. 10.1107/S0108768190011041 CASPubMedWeb of Science®Google Scholar 8K. Kamata, K. Yonehara, Y. Sumida, K. Yamaguchi, S. Hikichi, N. Mizuno, Science 2003, 300, 964–966. 10.1126/science.1083176 CASPubMedWeb of Science®Google Scholar 9B. Hedman, Acta Chem. Scand. Ser. A 1978, 32, 439–446. 10.3891/acta.chem.scand.32a-0439 Web of Science®Google Scholar 10 10aG. M. Varga, E. Papaconstantinou, M. T. Pope, Inorg. Chem. 1970, 9, 662–667; 10.1021/ic50085a045 CASWeb of Science®Google Scholar 10bX. Lopez, C. Bo, J. M. Poblet, J. Am. Chem. Soc. 2002, 124, 12574–12582. 10.1021/ja020407z CASPubMedWeb of Science®Google Scholar 11R. K. Harris, C. T. G. Knight, J. Chem. Soc. Faraday Trans. 2 1983, 79, 1539–1561. 10.1039/F29837901539 CASWeb of Science®Google Scholar Citing Literature Volume118, Issue1December 16, 2005Pages 145-148 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. ReferencesRelatedInformation

Referência(s)