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Advanced chemical design with supported metal complexes for selective catalysis

2006; Royal Society of Chemistry; Issue: 27 Linguagem: Inglês

10.1039/b601507g

1364-548X

Mizuki Tada, Yasuhiro Iwasawa,

Mesoporous Materials and Catalysis

This review covers several recent topics of novel catalyst design with supported metal complexes on oxide surfaces for selective catalysis such as chiral self-dimerization to create asymmetric oxidative coupling catalysis, surface functionalization with achiral reagents to promote asymmetric catalysis, and molecular imprinting to design shape-selective catalysis. The new concepts and designs find wide applications to a variety of selective catalysts.