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Use of amino amides derived from proline as chiral ligands in the ruthenium(II)-catalyzed transfer hydrogenation reaction of ketones

2001; Elsevier BV; Volume: 42; Issue: 30 Linguagem: Inglês

10.1016/s0040-4039(01)00914-5

1873-3581

Hae Yoon Rhyoo, Young-Ae Yoon, Hee‐Jung Park, Young Keun Chung,

Surface Chemistry and Catalysis

We developed an efficient, easily available, and easy to use proline amide-based ruthenium(II) catalysts for the asymmetric hydride transfer reduction of prochiral ketones and e.e.s up to 98.8% have been measured.