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Efficient Oxidation of Methane to Methanol by Dioxygen Mediated by Tricopper Clusters

2013; Wiley; Volume: 52; Issue: 13 Linguagem: Inglês

10.1002/anie.201209846

1521-3773

Sunney I. Chan, Yu‐Jhang Lu, Penumaka Nagababu, Suman Maji, Mu‐Cheng Hung, Marianne M. Lee, I‐Jui Hsu, Pham Dinh Minh, Jeff C.‐H. Lai, Kok Yoah Ng, Sridevi Ramalingam, Steve S.‐F. Yu, Michael K. Chan,

Porphyrin and Phthalocyanine Chemistry

Angewandte Chemie International EditionVolume 52, Issue 13 p. 3731-3735 Communication Efficient Oxidation of Methane to Methanol by Dioxygen Mediated by Tricopper Clusters† Prof. Dr. Sunney I. Chan, Corresponding Author Prof. Dr. Sunney I. Chan sunneychan@yahoo.com Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan) Sunney I. Chan, Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)=== Steve S.-F. Yu, Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)=== Michael K. Chan, Department of Chemistry and Biochemistry, Ohio State University, Columbus, OH 43210 (USA)===Search for more papers by this authorYu-Jhang Lu, Yu-Jhang Lu Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)Search for more papers by this authorDr. Penumaka Nagababu, Dr. Penumaka Nagababu Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)Search for more papers by this authorDr. Suman Maji, Dr. Suman Maji Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)Search for more papers by this authorMu-Cheng Hung, Mu-Cheng Hung Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)Search for more papers by this authorMarianne M. Lee, Marianne M. Lee Department of Chemistry and Biochemistry, Ohio State University, Columbus, OH 43210 (USA)Search for more papers by this authorProf. Dr. I-Jui Hsu, Prof. Dr. I-Jui Hsu Department of Molecular Science and Engineering, National Taipei University of Technology, Taipei 10608 (Taiwan)Search for more papers by this authorPham Dinh Minh, Pham Dinh Minh Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)Search for more papers by this authorJeff C.-H. Lai, Jeff C.-H. Lai Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)Search for more papers by this authorKok Yoah Ng, Kok Yoah Ng Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)Search for more papers by this authorSridevi Ramalingam, Sridevi Ramalingam Department of Chemistry and Biochemistry, Ohio State University, Columbus, OH 43210 (USA)Search for more papers by this authorProf. Dr. Steve S.-F. Yu, Corresponding Author Prof. Dr. Steve S.-F. Yu sfyu@gate.sinica.edu.tw Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan) Sunney I. Chan, Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)=== Steve S.-F. Yu, Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)=== Michael K. Chan, Department of Chemistry and Biochemistry, Ohio State University, Columbus, OH 43210 (USA)===Search for more papers by this authorProf. Dr. Michael K. Chan, Corresponding Author Prof. Dr. Michael K. Chan chan@chemistry.ohio-state.edu Department of Chemistry and Biochemistry, Ohio State University, Columbus, OH 43210 (USA) Sunney I. Chan, Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)=== Steve S.-F. Yu, Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)=== Michael K. Chan, Department of Chemistry and Biochemistry, Ohio State University, Columbus, OH 43210 (USA)===Search for more papers by this author Prof. Dr. Sunney I. Chan, Corresponding Author Prof. Dr. Sunney I. Chan sunneychan@yahoo.com Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan) Sunney I. Chan, Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)=== Steve S.-F. Yu, Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)=== Michael K. Chan, Department of Chemistry and Biochemistry, Ohio State University, Columbus, OH 43210 (USA)===Search for more papers by this authorYu-Jhang Lu, Yu-Jhang Lu Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)Search for more papers by this authorDr. Penumaka Nagababu, Dr. Penumaka Nagababu Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)Search for more papers by this authorDr. Suman Maji, Dr. Suman Maji Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)Search for more papers by this authorMu-Cheng Hung, Mu-Cheng Hung Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)Search for more papers by this authorMarianne M. Lee, Marianne M. Lee Department of Chemistry and Biochemistry, Ohio State University, Columbus, OH 43210 (USA)Search for more papers by this authorProf. Dr. I-Jui Hsu, Prof. Dr. I-Jui Hsu Department of Molecular Science and Engineering, National Taipei University of Technology, Taipei 10608 (Taiwan)Search for more papers by this authorPham Dinh Minh, Pham Dinh Minh Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)Search for more papers by this authorJeff C.-H. Lai, Jeff C.-H. Lai Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)Search for more papers by this authorKok Yoah Ng, Kok Yoah Ng Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)Search for more papers by this authorSridevi Ramalingam, Sridevi Ramalingam Department of Chemistry and Biochemistry, Ohio State University, Columbus, OH 43210 (USA)Search for more papers by this authorProf. Dr. Steve S.-F. Yu, Corresponding Author Prof. Dr. Steve S.-F. Yu sfyu@gate.sinica.edu.tw Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan) Sunney I. Chan, Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)=== Steve S.-F. Yu, Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)=== Michael K. Chan, Department of Chemistry and Biochemistry, Ohio State University, Columbus, OH 43210 (USA)===Search for more papers by this authorProf. Dr. Michael K. Chan, Corresponding Author Prof. Dr. Michael K. Chan chan@chemistry.ohio-state.edu Department of Chemistry and Biochemistry, Ohio State University, Columbus, OH 43210 (USA) Sunney I. Chan, Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)=== Steve S.-F. Yu, Institute of Chemistry, Academia Sinica, Nankang, Taipei 11529 (Taiwan)=== Michael K. Chan, Department of Chemistry and Biochemistry, Ohio State University, Columbus, OH 43210 (USA)===Search for more papers by this author First published: 18 February 2013 https://doi.org/10.1002/anie.201209846Citations: 140 † This work is supported by funds from Academia Sinica and Ohio State University (OSU), and grants from the National Science Council of the Republic of China (NSC 95-2113M-001-046, 97-2113M-001-027, and 98-2113M-001-026 to S.I.C.; 96-2627M-001-006 and 97-2113M-001-006-MY3 to S.S.F.Y.). S.R. was supported by a summer research fellowship from the National Science Foundation, USA (DBI 0750631). We acknowledge the assistance of Dr. Jyh-Fu Lee and his staff at the National Synchrotron Radiation Research Center, Hsinchu, Taiwan with the X-ray absorption measurements. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract TONs of copper fun: There is considerable interest in developing catalysts to harness the abundant natural supply of methane for various industrial applications. Two tricopper complexes capable of mediating efficient oxidation of methane to methanol under ambient conditions were tested: a biomimetic tricopper complex (see figure) and a tricopper-peptide species derived from the particulate methane monooxygenase (pMMO) protein. Citing Literature Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description anie_201209846_sm_miscellaneous_information.pdf801.6 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume52, Issue13March 25, 2013Pages 3731-3735 RelatedInformation