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An evanescent field driven mono-molecular layer photoswitch: coordination and release of metallated macrocycles

2002; Royal Society of Chemistry; Issue: 10 Linguagem: Inglês

10.1039/b201870p

1364-548X

Michael J. Cook, Anne-Mette Nygård, Zhenxin Wang, David A. Russell,

Analytical Chemistry and Sensors

Photoswitching of 'on' and 'off' coordination sites in a self assembled monolayer containing the 4-(arylazo)pyridine chromophore has been achieved using the evanescent field and illustrated through coordination and photon induced release of zinc tetraphenylporphyrin.