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Atomic‐Scale Evidence for an Enhanced Catalytic Reactivity of Stretched Surfaces

2003; Wiley; Volume: 42; Issue: 25 Linguagem: Inglês

10.1002/anie.200250845

1521-3773

J. Wintterlin, Tomaso Zambelli, Johannes Trost, Jeffrey Greeley, Manos Mavrikakis,

Machine Learning in Materials Science

Angewandte Chemie International EditionVolume 42, Issue 25 p. 2850-2853 Communication Atomic-Scale Evidence for an Enhanced Catalytic Reactivity of Stretched Surfaces† Joost Wintterlin Prof. Dr., Joost Wintterlin Prof. Dr. wintterlin@cup.uni-muenchen.de Fritz-Haber-Institut, Max-Planck-Gesellschaft, 14195 Berlin, Germany Current address:, Department Chemie, Univerisität München, 81377 München, Germany, Fax: (+49) 89-2180-77598Search for more papers by this authorTomaso Zambelli Dr., Tomaso Zambelli Dr. Fritz-Haber-Institut, Max-Planck-Gesellschaft, 14195 Berlin, GermanySearch for more papers by this authorJ. Trost Dr., J. Trost Dr. Fritz-Haber-Institut, Max-Planck-Gesellschaft, 14195 Berlin, GermanySearch for more papers by this authorJeffrey Greeley, Jeffrey Greeley Department of Chemical Engineering, University of Wisconsin, Madison, WI 53706-1691, USA, Fax: (+1) 608-262-5434Search for more papers by this authorManos Mavrikakis Prof., Manos Mavrikakis Prof. manos@engr.wisc.edu Department of Chemical Engineering, University of Wisconsin, Madison, WI 53706-1691, USA, Fax: (+1) 608-262-5434Search for more papers by this author Joost Wintterlin Prof. Dr., Joost Wintterlin Prof. Dr. wintterlin@cup.uni-muenchen.de Fritz-Haber-Institut, Max-Planck-Gesellschaft, 14195 Berlin, Germany Current address:, Department Chemie, Univerisität München, 81377 München, Germany, Fax: (+49) 89-2180-77598Search for more papers by this authorTomaso Zambelli Dr., Tomaso Zambelli Dr. Fritz-Haber-Institut, Max-Planck-Gesellschaft, 14195 Berlin, GermanySearch for more papers by this authorJ. Trost Dr., J. Trost Dr. Fritz-Haber-Institut, Max-Planck-Gesellschaft, 14195 Berlin, GermanySearch for more papers by this authorJeffrey Greeley, Jeffrey Greeley Department of Chemical Engineering, University of Wisconsin, Madison, WI 53706-1691, USA, Fax: (+1) 608-262-5434Search for more papers by this authorManos Mavrikakis Prof., Manos Mavrikakis Prof. manos@engr.wisc.edu Department of Chemical Engineering, University of Wisconsin, Madison, WI 53706-1691, USA, Fax: (+1) 608-262-5434Search for more papers by this author First published: 24 June 2003 https://doi.org/10.1002/anie.200250845Citations: 55 † T.Z. thanks the DAAD for financial support. M.M. thanks a NSF-CAREER award (CTS-0134561), and NSF-NPACI and DOE-NERSC for supercomputing time. We thank Lars Grabow for help with the graphics. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract NO can't take the strain: NO molecules are observed to preferentially dissociate near edge dislocations which originate in the bulk phase and intersect the metal surface. The effect is caused by lattice strain, a phenomenon in heterogeneous catalysis, which has been postulated for a long time and is demonstrated here on the atomic scale by calculations and STM images (see picture of two edge dislocations; black points: N atoms). Citing Literature Volume42, Issue25June 30, 2003Pages 2850-2853 RelatedInformation