The Handy Use of Brown’s P2‐Ni Catalyst for a Skipped Diyne Deuteration: Application to the Synthesis of a [D 4 ]‐Labeled F 4t ‐Neuroprostane
2010; Wiley; Volume: 16; Issue: 47 Linguagem: Inglês
10.1002/chem.201002304
ISSN1521-3765
AutoresCamille Oger, Valérie Bultel‐Poncé, Alexandre Guy, Laurence Balas, Jean‐Claude Rossi, Thierry Durand, Jean‐Marie Galano,
Tópico(s)Fluorine in Organic Chemistry
ResumoBrown's P2-Ni does the job: An efficient synthesis of tetradeuterated neuroprostane (see structure) has been accomplished by using an ene–diyne stereoselective deuteration strategy. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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